{"id":8817,"date":"2025-05-09T19:18:17","date_gmt":"2025-05-09T11:18:17","guid":{"rendered":"https:\/\/www.shorro.cn\/index.php\/archives\/8817"},"modified":"2025-05-09T19:18:17","modified_gmt":"2025-05-09T11:18:17","slug":"%e5%88%86%e6%9e%90%e5%85%89%e4%bc%8f%e8%86%9c%e7%94%a8%e8%bf%87%e6%b0%a7%e5%8c%96%e7%89%a9%e7%9a%84%e5%88%86%e8%a7%a3%e6%b8%a9%e5%ba%a6%e5%92%8c%e6%b4%bb%e5%8c%96%e8%83%bd","status":"publish","type":"post","link":"https:\/\/www.shorro.cn\/index.php\/archives\/8817","title":{"rendered":"\u5206\u6790\u5149\u4f0f\u819c\u7528\u8fc7\u6c27\u5316\u7269\u7684\u5206\u89e3\u6e29\u5ea6\u548c\u6d3b\u5316\u80fd"},"content":{"rendered":"

\u5149\u4f0f\u819c\u7528\u8fc7\u6c27\u5316\u7269\u7684\u5206\u89e3\u6e29\u5ea6\u4e0e\u6d3b\u5316\u80fd\uff1a\u4e00\u573a\u201c\u70ed\u604b\u201d\u4e2d\u7684\u5316\u5b66\u5192\u9669<\/h1>\n
\n

\u5f15\u5b50\uff1a\u5f53\u592a\u9633\u9047\u89c1\u7845\uff0c\u5316\u5b66\u6210\u4e86\u5e55\u540e\u82f1\u96c4 \ud83c\udf1e\u2728<\/h2>\n

\u5728\u9633\u5149\u707f\u70c2\u7684\u65e5\u5b50\u91cc\uff0c\u6211\u4eec\u62ac\u5934\u671b\u5929\uff0c\u770b\u5230\u7684\u662f\u6e29\u6696\u3001\u662f\u5e0c\u671b\u3002\u4f46\u4f60\u662f\u5426\u60f3\u8fc7\uff0c\u90a3\u7247\u95ea\u95ea\u53d1\u5149\u7684\u5149\u4f0f\u677f\u80cc\u540e\uff0c\u85cf\u7740\u591a\u5c11\u4e0d\u4e3a\u4eba\u77e5\u7684\u5316\u5b66\u6545\u4e8b\uff1f\u5c24\u5176\u662f\u90a3\u4e9b\u7528\u4e8e\u5236\u9020\u5149\u4f0f\u819c\u7684\u8fc7\u6c27\u5316\u7269\u4eec\uff0c\u5b83\u4eec\u50cf\u6781\u4e86\u604b\u7231\u4e2d\u7684\u4eba\u2014\u2014\u65e2\u70ed\u60c5\u53c8\u654f\u611f\uff0c\u7a0d\u6709\u4e0d\u614e\u5c31\u53ef\u80fd\u201c\u5206\u624b\u201d\uff0c\u751a\u81f3\u201c\u7206\u70b8\u201d\u3002\ud83d\udd25\ud83d\udca5<\/p>\n

\u4eca\u5929\uff0c\u6211\u4eec\u5c31\u6765\u804a\u804a\u8fd9\u4e9b\u201c\u5316\u5b66\u60c5\u4fa3\u201d\u4e2d\u5173\u952e\u7684\u4e00\u5bf9\u2014\u2014\u5206\u89e3\u6e29\u5ea6<\/strong>\u548c\u6d3b\u5316\u80fd<\/strong>\u3002\u5b83\u4eec\u4e0d\u4ec5\u51b3\u5b9a\u4e86\u8fc7\u6c27\u5316\u7269\u80fd\u5426\u987a\u5229\u5b8c\u6210\u4f7f\u547d\uff0c\u8fd8\u76f4\u63a5\u5f71\u54cd\u7740\u5149\u4f0f\u819c\u7684\u8d28\u91cf\u4e0e\u5bff\u547d\u3002<\/p>\n

\u51c6\u5907\u597d\u4e86\u5417\uff1f\u8ba9\u6211\u4eec\u4e00\u8d77\u8d70\u8fdb\u8fd9\u573a\u201c\u70ed\u604b\u201d\u7684\u79d1\u5b66\u4e16\u754c\u5427\uff01\ud83e\uddec\ud83e\uddea<\/p>\n


\n

\u7b2c\u4e00\u7ae0\uff1a\u8fc7\u6c27\u5316\u7269\u7684\u524d\u4e16\u4eca\u751f \u2014\u2014 \u5b83\u4eec\u90fd\u6765\u81ea\u54ea\u91cc\uff1f<\/h2>\n

1.1 \u8fc7\u6c27\u5316\u7269\u662f\u8c01\uff1f<\/h3>\n

\u8fc7\u6c27\u5316\u7269\uff08Peroxide\uff09\u662f\u4e00\u7c7b\u542b\u6709\u4e24\u4e2a\u6c27\u539f\u5b50\u4ee5\u5355\u952e\u8fde\u63a5\u7684\u5316\u5408\u7269\uff0c\u5e38\u89c1\u7684\u5982\u8fc7\u6c27\u5316\u6c22\uff08H\u2082O\u2082\uff09\u3001\u8fc7\u6c27\u5316\u4e8c\u82ef\u7532\u9170\uff08BPO\uff09\u3001\u8fc7\u6c27\u5316\u4e8c\u53d4\u4e01\u57fa\uff08DTBP\uff09\u7b49\u3002\u5b83\u4eec\u5e7f\u6cdb\u5e94\u7528\u4e8e\u805a\u5408\u53cd\u5e94\u3001\u4ea4\u8054\u5242\u3001\u56fa\u5316\u5242\u7b49\u9886\u57df\uff0c\u5c24\u5176\u5728\u5149\u4f0f\u819c\u6750\u6599\u7684\u5236\u5907\u4e2d\u626e\u6f14\u7740\u81f3\u5173\u91cd\u8981\u7684\u89d2\u8272\u3002<\/p>\n

\n

\ud83d\udca1\u5c0f\u8d34\u58eb\uff1a\u8fc7\u6c27\u5316\u7269\u5c31\u50cf\u7231\u60c5\u4e2d\u7684\u50ac\u5316\u5242\uff0c\u5b83\u672c\u8eab\u4e0d\u4e00\u5b9a\u53c2\u4e0e\u7ec8\u4ea7\u7269\uff0c\u4f46\u5374\u80fd\u5927\u5927\u52a0\u901f\u53cd\u5e94\u8fc7\u7a0b\uff01\n<\/p>\n<\/blockquote>\n

1.2 \u5149\u4f0f\u819c\u4e3a\u4f55\u79bb\u4e0d\u5f00\u5b83\uff1f<\/h3>\n

\u5728\u5149\u4f0f\u7ec4\u4ef6\u4e2d\uff0cEVA\uff08\u4e59\u70ef-\u918b\u9178\u4e59\u70ef\u5171\u805a\u7269\uff09\u662f\u5e38\u7528\u7684\u5c01\u88c5\u6750\u6599\u4e4b\u4e00\u3002\u4e3a\u4e86\u4f7fEVA\u5728\u9ad8\u6e29\u4e0b\u53d1\u751f\u4ea4\u8054\u53cd\u5e94\uff0c\u5f62\u6210\u7a33\u5b9a\u7684\u4e09\u7ef4\u7f51\u7edc\u7ed3\u6784\uff0c\u5fc5\u987b\u4f7f\u7528\u8fc7\u6c27\u5316\u7269\u4f5c\u4e3a\u5f15\u53d1\u5242\u3002\u800c\u8fd9\u4e2a\u8fc7\u7a0b\u7684\u5173\u952e\uff0c\u5c31\u5728\u4e8e\u8fc7\u6c27\u5316\u7269\u7684\u5206\u89e3\u884c\u4e3a<\/strong>\u3002<\/p>\n\n\n\n\n\n\n\n\n
\u5e38\u89c1\u5149\u4f0f\u819c\u7528\u8fc7\u6c27\u5316\u7269\u53ca\u5176\u7528\u9014<\/th>\n<\/tr>\n<\/thead>\n
\u540d\u79f0<\/td>\n\u5206\u5b50\u5f0f<\/td>\n\u4e3b\u8981\u7528\u9014<\/td>\n<\/tr>\n
\u8fc7\u6c27\u5316\u4e8c\u82ef\u7532\u9170<\/td>\n(C\u2086H\u2085CO)\u2082O\u2082<\/td>\nEVA\u4ea4\u8054\u3001\u81ea\u7531\u57fa\u5f15\u53d1\u5242<\/td>\n<\/tr>\n
\u8fc7\u6c27\u5316\u4e8c\u53d4\u4e01\u57fa<\/td>\n(CH\u2083)\u2083COOC(CH\u2083)\u2083<\/td>\n\u70ed\u5851\u6027\u6811\u8102\u4ea4\u8054<\/td>\n<\/tr>\n
\u8fc7\u6c27\u5316\u6708\u6842\u9170<\/td>\nC\u2081\u2082H\u2082\u2084O\u2084<\/td>\nPVC\u7a33\u5b9a\u5242\u3001\u6a61\u80f6\u786b\u5316\u5242<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n
\n

\u7b2c\u4e8c\u7ae0\uff1a\u5206\u89e3\u6e29\u5ea6\u2014\u2014\u8fc7\u6c27\u5316\u7269\u7684\u201c\u4e34\u754c\u70b9\u201d<\/h2>\n

2.1 \u5206\u89e3\u6e29\u5ea6\u662f\u4ec0\u4e48\uff1f<\/h3>\n

\u5206\u89e3\u6e29\u5ea6\uff08Decomposition Temperature\uff09\uff0c\u987e\u540d\u601d\u4e49\uff0c\u5c31\u662f\u8fc7\u6c27\u5316\u7269\u5f00\u59cb\u53d1\u751f\u5206\u89e3\u53cd\u5e94\u7684\u6e29\u5ea6\u3002\u4e00\u65e6\u8fbe\u5230\u8fd9\u4e2a\u6e29\u5ea6\uff0c\u5b83\u5c31\u4f1a\u91ca\u653e\u51fa\u6d3b\u6027\u81ea\u7531\u57fa\uff0c\u542f\u52a8\u540e\u7eed\u7684\u4ea4\u8054\u6216\u805a\u5408\u53cd\u5e94\u3002<\/p>\n

\n

\ud83d\udd25\u4e00\u53e5\u8bdd\u603b\u7ed3\uff1a\u5206\u89e3\u6e29\u5ea6 = \u5316\u5b66\u53cd\u5e94\u7684\u201c\u5bfc\u706b\u7d22\u201d\u3002\n<\/p>\n<\/blockquote>\n

2.2 \u4e0d\u540c\u8fc7\u6c27\u5316\u7269\u7684\u5206\u89e3\u6e29\u5ea6\u5bf9\u6bd4<\/h3>\n\n\n\n\n\n\n\n
\u8fc7\u6c27\u5316\u7269\u540d\u79f0<\/th>\n\u5206\u89e3\u6e29\u5ea6\u8303\u56f4\uff08\u2103\uff09<\/th>\n\u6d3b\u5316\u80fd\uff08kJ\/mol\uff09<\/th>\n\u7279\u70b9<\/th>\n<\/tr>\n<\/thead>\n
\u8fc7\u6c27\u5316\u4e8c\u82ef\u7532\u9170\uff08BPO\uff09<\/td>\n80~100<\/td>\n130<\/td>\n\u9ad8\u6d3b\u6027\uff0c\u9002\u5408\u4f4e\u6e29\u4ea4\u8054<\/td>\n<\/tr>\n
\u8fc7\u6c27\u5316\u4e8c\u53d4\u4e01\u57fa\uff08DTBP\uff09<\/td>\n120~140<\/td>\n150<\/td>\n\u7a33\u5b9a\u6027\u597d\uff0c\u9002\u7528\u4e8e\u9ad8\u6e29\u5de5\u827a<\/td>\n<\/tr>\n
\u8fc7\u6c27\u5316\u6708\u6842\u9170\uff08LPO\uff09<\/td>\n60~80<\/td>\n110<\/td>\n\u5206\u89e3\u5feb\uff0c\u5e38\u7528\u4e8e\u5feb\u901f\u786b\u5316\u4f53\u7cfb<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n
\n

\u26a0\ufe0f\u6ce8\u610f\uff1a\u9009\u62e9\u5408\u9002\u7684\u5206\u89e3\u6e29\u5ea6\u81f3\u5173\u91cd\u8981\uff0c\u592a\u9ad8\u4f1a\u63d0\u524d\u53cd\u5e94\uff0c\u592a\u4f4e\u5219\u65e0\u6cd5\u5f15\u53d1\u4ea4\u8054\u3002\n<\/p>\n<\/blockquote>\n


\n

\u7b2c\u4e09\u7ae0\uff1a\u6d3b\u5316\u80fd\u2014\u2014\u5316\u5b66\u53cd\u5e94\u7684\u201c\u5165\u573a\u5238\u201d<\/h2>\n

3.1 \u6d3b\u5316\u80fd\u7684\u6982\u5ff5<\/h3>\n

\u6d3b\u5316\u80fd\uff08Activation Energy, Ea\uff09\u662f\u6307\u5206\u5b50\u4ece\u5e38\u6001\u8f6c\u53d8\u4e3a\u8fc7\u6e21\u6001\u6240\u9700\u5438\u6536\u7684\u5c0f\u80fd\u91cf\u3002\u7b80\u5355\u6765\u8bf4\uff0c\u5b83\u662f\u53cd\u5e94\u53d1\u751f\u7684\u201c\u95e8\u69db\u201d\u3002\u8fc7\u6c27\u5316\u7269\u7684\u6d3b\u5316\u80fd\u8d8a\u4f4e\uff0c\u5176\u5206\u89e3\u901f\u5ea6\u5c31\u8d8a\u5feb\uff1b\u53cd\u4e4b\uff0c\u5219\u66f4\u7a33\u5b9a\u3002<\/p>\n

\n

\ud83e\udde0\u79d1\u666e\u65f6\u95f4\uff1a\u4f60\u53ef\u4ee5\u628a\u6d3b\u5316\u80fd\u60f3\u8c61\u6210\u4e00\u9053\u95e8\uff0c\u53ea\u6709\u8de8\u8fc7\u53bb\u624d\u80fd\u8fdb\u5165\u201c\u53cd\u5e94\u5927\u5385\u201d\u3002\n<\/p>\n<\/blockquote>\n

3.2 \u6d3b\u5316\u80fd\u4e0e\u5206\u89e3\u6e29\u5ea6\u7684\u5173\u7cfb<\/h3>\n

\u4e8c\u8005\u4e4b\u95f4\u5e76\u975e\u5b8c\u5168\u7ebf\u6027\u5173\u7cfb\uff0c\u4f46\u4e00\u822c\u6765\u8bf4\uff1a<\/p>\n

    \n
  • \u9ad8\u6d3b\u5316\u80fd \u2192 \u9ad8\u5206\u89e3\u6e29\u5ea6 \u2192 \u66f4\u7a33\u5b9a<\/strong><\/li>\n
  • \u4f4e\u6d3b\u5316\u80fd \u2192 \u4f4e\u5206\u89e3\u6e29\u5ea6 \u2192 \u6613\u5206\u89e3<\/strong><\/li>\n<\/ul>\n

    \u8fd9\u5c31\u597d\u6bd4\u8c08\u604b\u7231\uff0c\u6709\u4e9b\u4eba\u9700\u8981\u6162\u6162\u5347\u6e29\uff08\u9ad8\u6d3b\u5316\u80fd\uff09\uff0c\u6709\u4e9b\u4eba\u4e00\u70b9\u5c31\u7740\uff08\u4f4e\u6d3b\u5316\u80fd\uff09\u3002\u9009\u62e9\u4f34\u4fa3\u65f6\uff0c\u5f97\u770b\u573a\u5408\uff0c\u4e5f\u5f97\u770b\u6e29\u5ea6\u3002<\/p>\n


    \n

    \u7b2c\u56db\u7ae0\uff1a\u5b9e\u6218\u6848\u4f8b\u5206\u6790\u2014\u2014\u8c01\u66f4\u9002\u5408\u5149\u4f0f\u819c\uff1f<\/h2>\n

    4.1 BPO vs DTBP\uff1a\u4e00\u573a\u5173\u4e8e\u7a33\u5b9a\u6027\u4e0e\u6548\u7387\u7684\u8f83\u91cf<\/h3>\n\n\n\n\n\n\n\n\n\n
    \u5bf9\u6bd4\u7ef4\u5ea6<\/th>\nBPO<\/th>\nDTBP<\/th>\n<\/tr>\n<\/thead>\n
    \u5206\u89e3\u6e29\u5ea6<\/td>\n80~100 \u2103<\/td>\n120~140 \u2103<\/td>\n<\/tr>\n
    \u6d3b\u5316\u80fd<\/td>\n130 kJ\/mol<\/td>\n150 kJ\/mol<\/td>\n<\/tr>\n
    \u53cd\u5e94\u901f\u7387<\/td>\n\u5feb<\/td>\n\u4e2d\u7b49<\/td>\n<\/tr>\n
    \u7a33\u5b9a\u6027<\/td>\n\u4e00\u822c<\/td>\n\u9ad8<\/td>\n<\/tr>\n
    \u5e94\u7528\u573a\u666f<\/td>\n\u4f4e\u6e29\u4ea4\u8054\u3001\u5feb\u901f\u56fa\u5316<\/td>\n\u9ad8\u6e29\u4ea4\u8054\u3001\u957f\u671f\u7a33\u5b9a<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n
    \n

    \ud83e\udd14\u7ed3\u8bba\uff1a\u5982\u679c\u4f60\u8ffd\u6c42\u5feb\u901f\u4ea4\u8054\u3001\u6210\u672c\u63a7\u5236\uff0c\u9009BPO\uff1b\u82e5\u6ce8\u91cd\u7a33\u5b9a\u6027\u4e0e\u8010\u5019\u6027\uff0cDTBP\u66f4\u5408\u9002\u3002\n<\/p>\n<\/blockquote>\n


    \n

    \u7b2c\u4e94\u7ae0\uff1a\u5982\u4f55\u6d4b\u91cf\u5206\u89e3\u6e29\u5ea6\u4e0e\u6d3b\u5316\u80fd\uff1f<\/h2>\n

    5.1 \u5dee\u793a\u626b\u63cf\u91cf\u70ed\u6cd5\uff08DSC\uff09<\/h3>\n

    \u8fd9\u662f\u76ee\u524d\u5e38\u7528\u7684\u65b9\u6cd5\u4e4b\u4e00\u3002\u901a\u8fc7\u52a0\u70ed\u6837\u54c1\u5e76\u8bb0\u5f55\u70ed\u91cf\u53d8\u5316\uff0c\u53ef\u4ee5\u7cbe\u786e\u6d4b\u5b9a\u5206\u89e3\u6e29\u5ea6\u3002<\/p>\n

    \n

    \ud83d\udcca\u56fe\u8868\u793a\u4f8b\uff08\u6a21\u62df\u6570\u636e\uff09\uff1a\n<\/p>\n<\/blockquote>\n\n\n\n\n\n\n\n\n
    \u6e29\u5ea6\uff08\u2103\uff09<\/th>\n\u70ed\u6d41\uff08mW\/mg\uff09<\/th>\n<\/tr>\n<\/thead>\n
    60<\/td>\n-0.2<\/td>\n<\/tr>\n
    80<\/td>\n-1.5<\/td>\n<\/tr>\n
    100<\/td>\n-3.0<\/td>\n<\/tr>\n
    120<\/td>\n-4.2<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n
    \n

    \ud83d\udcc8\u8d8b\u52bf\uff1a\u968f\u7740\u6e29\u5ea6\u5347\u9ad8\uff0c\u70ed\u6d41\u8d1f\u503c\u589e\u5927\uff0c\u8bf4\u660e\u5206\u89e3\u53cd\u5e94\u5f00\u59cb\u8fdb\u884c\u3002<\/p>\n<\/blockquote>\n

    5.2 \u52a8\u529b\u5b66\u65b9\u6cd5\uff08Kissinger \u6cd5\uff09<\/h3>\n

    \u5229\u7528\u4e0d\u540c\u5347\u6e29\u901f\u7387\u4e0b\u7684DSC\u6570\u636e\uff0c\u7ed3\u5408\u516c\u5f0f\u8ba1\u7b97\u6d3b\u5316\u80fd\uff1a<\/p>\n

    \"$title[$i]\"<\/p>\n<\/blockquote>\n

    5.2 \u52a8\u529b\u5b66\u65b9\u6cd5\uff08Kissinger \u6cd5\uff09<\/h3>\n

    \u5229\u7528\u4e0d\u540c\u5347\u6e29\u901f\u7387\u4e0b\u7684DSC\u6570\u636e\uff0c\u7ed3\u5408\u516c\u5f0f\u8ba1\u7b97\u6d3b\u5316\u80fd\uff1a<\/p>\n

    $$
    \nln left( frac{beta}{T_p^2} right) = text{\u5e38\u6570} – frac{E_a}{R T_p}
    \n$$<\/p>\n

    \u5176\u4e2d\uff1a<\/p>\n