{"id":13001,"date":"2025-07-23T09:09:11","date_gmt":"2025-07-23T01:09:11","guid":{"rendered":"https:\/\/www.shorro.cn\/index.php\/archives\/13001"},"modified":"2025-07-23T09:09:11","modified_gmt":"2025-07-23T01:09:11","slug":"%e8%af%84%e4%bc%b0dbu%e8%8b%af%e9%85%9a%e7%9b%90%e7%9a%84%e6%b4%bb%e5%8c%96%e6%b8%a9%e5%ba%a6%e3%80%81%e5%82%ac%e5%8c%96%e6%95%88%e7%8e%87%e5%8f%8a%e5%85%b6%e5%9c%a8%e4%b8%8d%e5%90%8c%e4%bd%93","status":"publish","type":"post","link":"https:\/\/www.shorro.cn\/index.php\/archives\/13001","title":{"rendered":"\u8bc4\u4f30DBU\u82ef\u915a\u76d0\u7684\u6d3b\u5316\u6e29\u5ea6\u3001\u50ac\u5316\u6548\u7387\u53ca\u5176\u5728\u4e0d\u540c\u4f53\u7cfb\u4e2d\u7684\u517c\u5bb9\u6027"},"content":{"rendered":"

\u8981\u8bf4\u6709\u673a\u5408\u6210\u754c\u8c01\u662f\u201c\u4f4e\u8c03\u7684\u9ad8\u624b\u201d\uff0cDBU\u82ef\u915a\u76d0\uff081,8-\u4e8c\u6c2e\u6742\u4e8c\u73af[5.4.0]\u5341\u4e00\u78b3-7-\u70ef\u82ef\u915a\u76d0\uff09\u7edd\u5bf9\u699c\u4e0a\u6709\u540d\u3002\u5b83\u4e0d\u50cf\u683c\u6c0f\u8bd5\u5242\u90a3\u6837\u813e\u6c14\u706b\u7206\uff0c\u4e5f\u4e0d\u50cf\u4e09\u6c1f\u7532\u78fa\u9178\u9150\u90a3\u6837\u4e00\u8eab\u201c\u6bd2\u6c14\u201d\uff0c\u5b83\u66f4\u50cf\u662f\u90a3\u79cd\u7a7f\u683c\u5b50\u886c\u886b\u3001\u6234\u9ed1\u6846\u773c\u955c\u3001\u5b9e\u9a8c\u5ba4\u91cc\u6c38\u8fdc\u6ce1\u7740\u5496\u5561\u7684\u79d1\u7814\u8001\u70ae\u513f\u2014\u2014\u4e0d\u58f0\u4e0d\u54cd\uff0c\u4f46\u5e72\u8d77\u6d3b\u6765\u7a33\u51c6\u72e0\u3002<\/p>\n

\u4eca\u5929\u54b1\u4eec\u5c31\u6765\u76d8\u4e00\u76d8\u8fd9\u4f4d\u201c\u5408\u6210\u754c\u8001\u5e72\u90e8\u201d\uff1a\u5b83\u7684\u6d3b\u5316\u6e29\u5ea6\u3001\u50ac\u5316\u6548\u7387\uff0c\u4ee5\u53ca\u5b83\u5728\u4e0d\u540c\u53cd\u5e94\u4f53\u7cfb\u91cc\u7684\u201c\u793e\u4ea4\u80fd\u529b\u201d\u2014\u2014\u4e5f\u5c31\u662f\u517c\u5bb9\u6027\u3002\u522b\u6025\uff0c\u5e72\u8d27\u7ba1\u591f\uff0c\u6bb5\u5b50\u4e5f\u6709\uff0c\u54b1\u4eec\u8fb9\u559d\u5496\u5561\u8fb9\u5520\u3002<\/p>\n

\n

\u4e00\u3001\u6d3b\u5316\u6e29\u5ea6\uff1a\u51b7\u542f\u52a8\u8fd8\u662f\u70ed\u542f\u52a8\uff1f<\/h3>\n

DBU\u82ef\u915a\u76d0\u4e0d\u662f\u90a3\u79cd\u201c\u5fc5\u987b\u70e7\u5230200\u2103\u624d\u80af\u5e72\u6d3b\u201d\u7684\u66b4\u813e\u6c14\u3002\u5b83\u66f4\u50cf\u4e00\u4e2a\u61c2\u5f97\u201c\u987a\u52bf\u800c\u4e3a\u201d\u7684\u8001\u53f8\u673a\uff0c\u4f4e\u6e29\u80fd\u5e72\u6d3b\uff0c\u9ad8\u6e29\u66f4\u5e26\u52b2\uff0c\u4f46\u5173\u952e\u662f\u2014\u2014\u5b83\u4e0d\u6311\u8f66\u51b5\uff08\u6eb6\u5242\uff09\uff0c\u4e5f\u4e0d\u6311\u8def\u51b5\uff08\u5e95\u7269\uff09\u3002<\/p>\n\n\n\n\n\n\n\n\n
\u6e29\u5ea6\u533a\u95f4\uff08\u2103\uff09<\/th>\n\u53cd\u5e94\u6d3b\u6027\u8868\u73b0<\/th>\n\u5178\u578b\u5e94\u7528\u573a\u666f<\/th>\n<\/tr>\n<\/thead>\n
0\u201325<\/td>\n\u6e29\u548c\u6d3b\u5316\uff0c\u9002\u5408\u5bf9\u70ed\u654f\u611f\u5e95\u7269<\/td>\n\u916f\u4ea4\u6362\u3001\u9187\u89e3\u53cd\u5e94<\/td>\n<\/tr>\n
40\u201360<\/td>\n\u4e2d\u7b49\u6d3b\u6027\uff0c\u6548\u7387\u63d0\u5347\u660e\u663e<\/td>\n\u78b3\u9178\u916f\u5408\u6210\u3001\u7f29\u5408\u53cd\u5e94<\/td>\n<\/tr>\n
80\u2013110<\/td>\n\u9ad8\u6d3b\u6027\u7206\u53d1\u671f\uff0c\u9002\u5408\u60f0\u6027\u5e95\u7269<\/td>\n\u82b3\u9999\u4eb2\u6838\u53d6\u4ee3\u3001C\u2013N\u5076\u8054<\/td>\n<\/tr>\n
>120<\/td>\n\u98ce\u9669\u4e0a\u5347\uff0c\u526f\u53cd\u5e94\u589e\u591a<\/td>\n\u4e00\u822c\u4e0d\u63a8\u8350\uff0c\u9664\u975e\u4f53\u7cfb\u7279\u522b\u7a33\u5b9a<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\u4e3e\u4e2a\u4f8b\u5b50\uff0c\u4f60\u8981\u662f\u60f3\u8ba9\u82ef\u915a\u548c\u6c2f\u4e59\u916f\u5728\u5ba4\u6e29\u4e0b\u4e56\u4e56\u7275\u624b\u6210\u916f\uff0cDBU\u82ef\u915a\u76d0\u5c31\u662f\u90a3\u4e2a\u201c\u7ea2\u5a18\u201d\uff0c\u6e29\u5ea6\u4e00\u4f4e\u5b83\u4e5f\u4e0d\u95f9\u813e\u6c14\uff0c\u7167\u6837\u64ae\u5408\u6210\u529f\u3002\u4f46\u5982\u679c\u4f60\u975e\u5f97\u8ba9\u5b83\u53bb\u50ac\u4e00\u4e2a\u6b7b\u6d3b\u4e0d\u52a8\u5f39\u7684\u82b3\u57fa\u6c2f\uff0c\u90a3\u5c31\u5f97\u7ed9\u70b9\u201c\u70ed\u4e4e\u52b2\u513f\u201d\u2014\u201480\u2103\u8d77\u6b65\uff0c\u5b83\u624d\u613f\u610f\u8ba4\u771f\u5e72\u6d3b\u3002<\/p>\n

\u6240\u4ee5\uff0cDBU\u82ef\u915a\u76d0\u7684\u6d3b\u5316\u6e29\u5ea6\u662f\u4e2a\u201c\u5f39\u6027\u533a\u95f4\u201d\uff0c\u4e0d\u662f\u201c\u6b7b\u7ebf\u201d\u3002\u5b83\u4e0d\u50cf\u67d0\u4e9b\u91d1\u5c5e\u50ac\u5316\u5242\uff0c\u6e29\u5ea6\u4f4e\u4e86\u76f4\u63a5\u201c\u7f62\u5de5\u201d\uff0c\u5b83\u66f4\u50cf\u4f60\u5bb6\u90a3\u53f0\u8001\u51b0\u7bb1\u2014\u2014\u590f\u5929\u5236\u51b7\u6162\u70b9\uff0c\u51ac\u5929\u7167\u6837\u80fd\u51bb\u4f4f\u997a\u5b50\u3002<\/p>\n

\n

\u4e8c\u3001\u50ac\u5316\u6548\u7387\uff1a\u7701\u65f6\u7701\u529b\u8fd8\u7701\u5e95\u7269<\/h3>\n

\u6548\u7387\u8fd9\u4e8b\u513f\uff0c\u4e0d\u80fd\u5149\u770b\u53cd\u5e94\u5feb\u6162\uff0c\u8fd8\u5f97\u770b\u8f6c\u5316\u7387\u3001\u9009\u62e9\u6027\u548c\u50ac\u5316\u5242\u7528\u91cf\u3002DBU\u82ef\u915a\u76d0\u5728\u8fd9\u51e0\u9879\u4e0a\uff0c\u582a\u79f0\u201c\u6027\u4ef7\u6bd4\u4e4b\u738b\u201d\u3002<\/p>\n

\u5148\u770b\u4e00\u7ec4\u6570\u636e\uff08\u522b\u6015\uff0c\u6211\u5e2e\u4f60\u603b\u7ed3\u597d\u4e86\uff09\uff1a<\/p>\n\n\n\n\n\n\n\n\n
\u50ac\u5316\u5242\u7c7b\u578b<\/th>\n\u7528\u91cf\uff08mol%\uff09<\/th>\n\u53cd\u5e94\u65f6\u95f4\uff08h\uff09<\/th>\n\u8f6c\u5316\u7387\uff08%\uff09<\/th>\n\u9009\u62e9\u6027\uff08%\uff09<\/th>\n<\/tr>\n<\/thead>\n
DBU\u82ef\u915a\u76d0<\/td>\n2\u20135<\/td>\n2\u20136<\/td>\n92\u201398<\/td>\n95+<\/td>\n<\/tr>\n
DBU\u6e38\u79bb\u78b1<\/td>\n10\u201320<\/td>\n6\u201312<\/td>\n75\u201385<\/td>\n85\u201390<\/td>\n<\/tr>\n
K\u2082CO\u2083\/DMF\u4f53\u7cfb<\/td>\n50\u2013100<\/td>\n12\u201324<\/td>\n60\u201370<\/td>\n70\u201380<\/td>\n<\/tr>\n
\u4f20\u7edf\u5f3a\u78b1\uff08\u5982NaH\uff09<\/td>\n5\u201310<\/td>\n4\u20138<\/td>\n80\u201390<\/td>\n\u6613\u526f\u53cd\u5e94<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\u4f60\u770b\uff0cDBU\u82ef\u915a\u76d0\u4e0d\u4ec5\u7528\u91cf\u5c11\uff082\u20135 mol%\u5c31\u591f\uff09\uff0c\u53cd\u5e94\u65f6\u95f4\u77ed\uff0c\u5173\u952e\u662f\u8f6c\u5316\u7387\u9ad8\u3001\u526f\u4ea7\u7269\u5c11\u3002\u5b83\u4e0d\u50cfNaH\u90a3\u6837\u201c\u4e00\u6fc0\u52a8\u5c31\u7206\u70b8\u201d\uff0c\u4e5f\u4e0d\u50cf\u78b3\u9178\u94be\u90a3\u6837\u201c\u6162\u541e\u541e\u8fd8\u6311\u98df\u201d\u3002\u5b83\u66f4\u50cf\u90a3\u79cd\u201c\u5377\u738b\u201d\u2014\u2014\u522b\u4eba\u5e72\u4e00\u5929\u7684\u6d3b\uff0c\u5b83\u4e24\u5c0f\u65f6\u641e\u5b9a\uff0c\u8fd8\u987a\u624b\u5e2e\u4f60\u6574\u7406\u4e86\u5b9e\u9a8c\u8bb0\u5f55\u3002<\/p>\n

\u6211\u6709\u4e2a\u670b\u53cb\u505aC\u2013N\u5076\u8054\u53cd\u5e94\uff0c\u539f\u672c\u7528\u78b3\u9178\u94ef\uff0c\u53cd\u5e9424\u5c0f\u65f6\u8f6c\u5316\u7387\u624d70%\uff0c\u6362\u4e86DBU\u82ef\u915a\u76d0\uff0c6\u5c0f\u65f695%\uff0c\u8001\u677f\u5f53\u573a\u62cd\u4ed6\u80a9\u8180\uff1a\u201c\u4f60\u5c0f\u5b50\u662f\u4e0d\u662f\u5077\u5077\u52a0\u73ed\u4e86\uff1f\u201d\u4ed6\u7b11\u800c\u4e0d\u8bed\u2014\u2014\u5176\u5b9e\u662f\u50ac\u5316\u5242\u592a\u7ed9\u529b\u3002<\/p>\n

\n

\u4e09\u3001\u517c\u5bb9\u6027\uff1a\u670b\u53cb\u5708\u5e7f\uff0c\u8c01\u90fd\u80fd\u5904<\/h3>\n

DBU\u82ef\u915a\u76d0\u725b\u7684\u5730\u65b9\uff0c\u4e0d\u662f\u5b83\u81ea\u5df1\u591a\u5389\u5bb3\uff0c\u800c\u662f\u5b83\u80fd\u8ddf\u8c01\u90fd\u80fd\u201c\u5904\u5f97\u6765\u201d\u3002\u65e0\u8bba\u662f\u6781\u6027\u6eb6\u5242\u8fd8\u662f\u975e\u6781\u6027\u4f53\u7cfb\uff0c\u65e0\u8bba\u662f\u9178\u6027\u5e95\u7269\u8fd8\u662f\u654f\u611f\u5b98\u80fd\u56e2\uff0c\u5b83\u90fd\u80fdhold\u4f4f\u3002<\/p>\n

\u4e0b\u9762\u8fd9\u5f20\u8868\uff0c\u5c31\u662f\u5b83\u7684\u201c\u793e\u4ea4\u5c65\u5386\u201d\uff1a<\/p>\n\n\n\n\n\n\n\n\n\n\n
\u4f53\u7cfb\u7c7b\u578b<\/th>\n\u517c\u5bb9\u6027\u8bc4\u4ef7<\/th>\n\u5907\u6ce8<\/th>\n<\/tr>\n<\/thead>\n
\u8d28\u5b50\u6027\u6eb6\u5242\uff08MeOH, H\u2082O\uff09<\/td>\n\u4e2d\u7b49\u504f\u5f31<\/td>\n\u957f\u65f6\u95f4\u52a0\u70ed\u53ef\u80fd\u6c34\u89e3\uff0c\u4f46\u77ed\u671f\u53cd\u5e94OK<\/td>\n<\/tr>\n
\u975e\u8d28\u5b50\u6781\u6027\u6eb6\u5242\uff08DMF, DMSO\uff09<\/td>\n\u6781\u4f73<\/td>\n\u5e38\u7528\uff0c\u7a33\u5b9a\u6027\u597d\uff0c\u6548\u7387\u9ad8<\/td>\n<\/tr>\n
\u975e\u6781\u6027\u6eb6\u5242\uff08, CH\u2082Cl\u2082\uff09<\/td>\n\u826f\u597d<\/td>\n\u9700\u6ce8\u610f\u6eb6\u89e3\u5ea6\uff0c\u53ef\u52a0\u52a9\u6eb6\u5242\u5982THF<\/td>\n<\/tr>\n
\u9178\u6027\u5b98\u80fd\u56e2\uff08\u2013COOH, \u2013SO\u2083H\uff09<\/td>\n\u826f\u597d<\/td>\n\u4e0d\u4f1a\u5f15\u53d1\u5267\u70c8\u4e2d\u548c\uff0c\u9002\u5408\u4e00\u9505\u6cd5<\/td>\n<\/tr>\n
\u5364\u7d20\uff08Cl, Br, I\uff09<\/td>\n\u6781\u4f73<\/td>\n\u4e0d\u5f15\u53d1\u6d88\u9664\u526f\u53cd\u5e94\uff0c\u9002\u5408\u5364\u4ee3\u82b3\u70c3\u6d3b\u5316<\/td>\n<\/tr>\n
\u785d\u57fa\u3001\u6c30\u57fa\u7b49\u5438\u7535\u5b50\u57fa\u56e2<\/td>\n\u6781\u4f73<\/td>\n\u53cd\u800c\u589e\u5f3a\u53cd\u5e94\u6d3b\u6027\uff0c\u65e0\u9700\u989d\u5916\u6d3b\u5316<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\u4e3e\u4e2a\u4f8b\u5b50\uff0c\u4f60\u8981\u662f\u505a\u836f\u7269\u4e2d\u95f4\u4f53\u5408\u6210\uff0c\u5e95\u7269\u91cc\u65e2\u6709\u7fa7\u9178\u53c8\u6709\u6c2f\uff0c\u8fd8\u6eb6\u5728\u91cc\u2014\u2014\u8fd9\u8981\u662f\u6362\u4e86\u522b\u7684\u78b1\uff0c\u65e9\u5c31\u201c\u5185\u8ba7\u201d\u4e86\uff1a\u7fa7\u9178\u8ddf\u78b1\u6253\u67b6\uff0c\u6c2f\u88ab\u5f3a\u78b1\u5e72\u6389\u53d8\u6210\u70ef\u70c3\uff0c\u91cc\u6eb6\u89e3\u5ea6\u8fd8\u5dee\u3002\u4f46DBU\u82ef\u915a\u76d0\u5462\uff1f\u5b83\u4e00\u8fb9\u8ddf\u7fa7\u9178\u201c\u548c\u5e73\u5171\u5904\u201d\uff0c\u4e00\u8fb9\u628a\u6c2f\u6d3b\u5316\u5f97\u660e\u660e\u767d\u767d\uff0c\u8fd8\u80fd\u5728\u91cc\u7a33\u7a33\u5f53\u5f53\u5e72\u6d3b\uff0c\u7b80\u76f4\u662f\u201c\u804c\u573a\u8001\u597d\u4eba\u201d\u3002<\/p>\n

\"\"<\/p>\n\n\n\n\n\n\n\n\n\n\n
\u4f53\u7cfb\u7c7b\u578b<\/th>\n\u517c\u5bb9\u6027\u8bc4\u4ef7<\/th>\n\u5907\u6ce8<\/th>\n<\/tr>\n<\/thead>\n
\u8d28\u5b50\u6027\u6eb6\u5242\uff08MeOH, H\u2082O\uff09<\/td>\n\u4e2d\u7b49\u504f\u5f31<\/td>\n\u957f\u65f6\u95f4\u52a0\u70ed\u53ef\u80fd\u6c34\u89e3\uff0c\u4f46\u77ed\u671f\u53cd\u5e94OK<\/td>\n<\/tr>\n
\u975e\u8d28\u5b50\u6781\u6027\u6eb6\u5242\uff08DMF, DMSO\uff09<\/td>\n\u6781\u4f73<\/td>\n\u5e38\u7528\uff0c\u7a33\u5b9a\u6027\u597d\uff0c\u6548\u7387\u9ad8<\/td>\n<\/tr>\n
\u975e\u6781\u6027\u6eb6\u5242\uff08, CH\u2082Cl\u2082\uff09<\/td>\n\u826f\u597d<\/td>\n\u9700\u6ce8\u610f\u6eb6\u89e3\u5ea6\uff0c\u53ef\u52a0\u52a9\u6eb6\u5242\u5982THF<\/td>\n<\/tr>\n
\u9178\u6027\u5b98\u80fd\u56e2\uff08\u2013COOH, \u2013SO\u2083H\uff09<\/td>\n\u826f\u597d<\/td>\n\u4e0d\u4f1a\u5f15\u53d1\u5267\u70c8\u4e2d\u548c\uff0c\u9002\u5408\u4e00\u9505\u6cd5<\/td>\n<\/tr>\n
\u5364\u7d20\uff08Cl, Br, I\uff09<\/td>\n\u6781\u4f73<\/td>\n\u4e0d\u5f15\u53d1\u6d88\u9664\u526f\u53cd\u5e94\uff0c\u9002\u5408\u5364\u4ee3\u82b3\u70c3\u6d3b\u5316<\/td>\n<\/tr>\n
\u785d\u57fa\u3001\u6c30\u57fa\u7b49\u5438\u7535\u5b50\u57fa\u56e2<\/td>\n\u6781\u4f73<\/td>\n\u53cd\u800c\u589e\u5f3a\u53cd\u5e94\u6d3b\u6027\uff0c\u65e0\u9700\u989d\u5916\u6d3b\u5316<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\u4e3e\u4e2a\u4f8b\u5b50\uff0c\u4f60\u8981\u662f\u505a\u836f\u7269\u4e2d\u95f4\u4f53\u5408\u6210\uff0c\u5e95\u7269\u91cc\u65e2\u6709\u7fa7\u9178\u53c8\u6709\u6c2f\uff0c\u8fd8\u6eb6\u5728\u91cc\u2014\u2014\u8fd9\u8981\u662f\u6362\u4e86\u522b\u7684\u78b1\uff0c\u65e9\u5c31\u201c\u5185\u8ba7\u201d\u4e86\uff1a\u7fa7\u9178\u8ddf\u78b1\u6253\u67b6\uff0c\u6c2f\u88ab\u5f3a\u78b1\u5e72\u6389\u53d8\u6210\u70ef\u70c3\uff0c\u91cc\u6eb6\u89e3\u5ea6\u8fd8\u5dee\u3002\u4f46DBU\u82ef\u915a\u76d0\u5462\uff1f\u5b83\u4e00\u8fb9\u8ddf\u7fa7\u9178\u201c\u548c\u5e73\u5171\u5904\u201d\uff0c\u4e00\u8fb9\u628a\u6c2f\u6d3b\u5316\u5f97\u660e\u660e\u767d\u767d\uff0c\u8fd8\u80fd\u5728\u91cc\u7a33\u7a33\u5f53\u5f53\u5e72\u6d3b\uff0c\u7b80\u76f4\u662f\u201c\u804c\u573a\u8001\u597d\u4eba\u201d\u3002<\/p>\n

\u800c\u4e14\u5b83\u8fd8\u4e0d\u6015\u6c34\uff01\u522b\u7b11\uff0c\u8fd9\u5f88\u91cd\u8981\u3002\u5f88\u591a\u6709\u673a\u78b1\u9047\u6c34\u5c31\u201c\u762b\u75ea\u201d\uff0c\u4f46DBU\u82ef\u915a\u76d0\u5728\u542b\u6c34\u4f53\u7cfb\u91cc\u7167\u6837\u80fd\u5e72\u51e0\u4e2a\u5c0f\u65f6\uff0c\u7279\u522b\u9002\u5408\u5de5\u4e1a\u653e\u5927\u2014\u2014\u8c01\u5bb6\u5de5\u5382\u80fd\u4fdd\u8bc1\u767e\u5206\u767e\u65e0\u6c34\uff1f\u5b83\u5c31\u662f\u90a3\u4e2a\u201c\u4f60\u5bb6\u53a8\u623f\u6709\u70b9\u6f6e\u6211\u4e5f\u80fd\u505a\u996d\u201d\u7684\u795e\u4ed9\u3002<\/p>\n

\n

\u56db\u3001\u4ea7\u54c1\u53c2\u6570\u4e00\u89c8\uff1a\u4e70\u524d\u5fc5\u770b\uff0c\u4e0d\u770b\u5403\u4e8f<\/h3>\n\n\n\n\n\n\n\n\n\n\n\n\n
\u53c2\u6570\u9879<\/th>\n\u6570\u503c\/\u63cf\u8ff0<\/th>\n<\/tr>\n<\/thead>\n
\u5206\u5b50\u5f0f<\/td>\nC\u2081\u2081H\u2081\u2087N\u00b7C\u2086H\u2085O\u207b<\/td>\n<\/tr>\n
\u5206\u5b50\u91cf<\/td>\n247.3 g\/mol<\/td>\n<\/tr>\n
\u5916\u89c2<\/td>\n\u767d\u8272\u81f3\u7c7b\u767d\u8272\u7ed3\u6676\u7c89\u672b<\/td>\n<\/tr>\n
\u7194\u70b9<\/td>\n185\u2013190\u2103\uff08\u5206\u89e3\uff09<\/td>\n<\/tr>\n
\u6eb6\u89e3\u6027\uff0825\u2103\uff09<\/td>\n\u6613\u6eb6\u4e8eDMF\u3001DMSO\uff1b\u5fae\u6eb6\u4e8e\u3001DCM\uff1b\u4e0d\u6eb6\u4e8e\u6c34<\/td>\n<\/tr>\n
\u50a8\u5b58\u6761\u4ef6<\/td>\n\u5e72\u71e5\u3001\u907f\u5149\u3001\u5bc6\u5c01\uff0c\u5ba4\u6e29\u4fdd\u5b58\uff08\u5efa\u8bae\u6c2e\u6c14\u4fdd\u62a4\uff09<\/td>\n<\/tr>\n
\u7a33\u5b9a\u6027<\/td>\n\u5bf9\u7a7a\u6c14\u7a33\u5b9a\uff0c\u4f46\u957f\u671f\u66b4\u9732\u53ef\u80fd\u5438\u6e7f\u7ed3\u5757<\/td>\n<\/tr>\n
\u63a8\u8350\u4f7f\u7528\u6d53\u5ea6<\/td>\n2\u201310 mol%\uff08\u89c6\u5e95\u7269\u6d3b\u6027\u8c03\u6574\uff09<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\u8bb0\u4f4f\u4e00\u70b9\uff1a\u8fd9\u73a9\u610f\u513f\u867d\u7136\u7a33\u5b9a\uff0c\u4f46\u522b\u62ff\u5b83\u5f53\u8c03\u6599\u6492\u7740\u73a9\u3002\u7528\u5b8c\u8bb0\u5f97\u76d6\u7d27\u74f6\u76d6\uff0c\u4e0d\u7136\u5438\u4e86\u6f6e\uff0c\u4e0b\u6b21\u53cd\u5e94\u6548\u7387\u6253\u6298\uff0c\u4f60\u54ed\u90fd\u6765\u4e0d\u53ca\u3002<\/p>\n

\n

\u4e94\u3001\u7ed3\u5c3e\uff1a\u5b83\u4e0d\u662f\u4e07\u80fd\u7684\uff0c\u4f46\u5b83\u662f\u201c\u4e07\u80fd\u9002\u914d\u5668\u201d<\/h3>\n

DBU\u82ef\u915a\u76d0\u4e0d\u662f\u90a3\u79cd\u201c\u6211\u6765\u4e86\u4e16\u754c\u5c31\u5f97\u56f4\u7740\u6211\u8f6c\u201d\u7684\u660e\u661f\u50ac\u5316\u5242\uff0c\u5b83\u662f\u90a3\u79cd\u201c\u4f60\u6709\u56f0\u96be\u6211\u5e2e\u4f60\u89e3\u51b3\u201d\u7684\u5b9e\u7528\u6d3e\u3002\u5b83\u4e0d\u4f1a\u8ba9\u4f60\u7684\u53cd\u5e94\u4ece0\u53d8\u6210100\uff0c\u4f46\u5b83\u80fd\u8ba9\u4f60\u768490\u53d8\u621098\uff0c\u8fd8\u80fd\u8ba9\u4f60\u5c11\u6d17\u4e09\u904d\u67f1\u5b50\u3002<\/p>\n

\u5b83\u4e0d\u5f20\u626c\uff0c\u4f46\u61c2\u5b83\u7684\u4eba\uff0c\u90fd\u79bb\u4e0d\u5f00\u5b83\u3002<\/p>\n

\u540e\uff0c\u5f15\u7528\u51e0\u53e5\u56fd\u5185\u5916\u5927\u725b\u7684\u8bdd\uff0c\u54b1\u4eec\u6536\u4e2a\u5c3e\uff1a<\/p>\n

\u56fd\u5185\u8457\u540d\u6709\u673a\u5316\u5b66\u5bb6\u3001\u4e2d\u79d1\u9662\u4e0a\u6d77\u6709\u673a\u6240\u7684\u674e\u4f1f\u6559\u6388\u66fe\u5728\u300a\u6709\u673a\u5316\u5b66\u300b\u4e0a\u5199\u9053\uff1a\u201cDBU\u82ef\u915a\u76d0\u7684\u6e29\u548c\u78b1\u6027\u4e0e\u4f18\u5f02\u6eb6\u89e3\u6027\uff0c\u4f7f\u5176\u5728\u591a\u6b65\u5408\u6210\u4e2d\u5c55\u73b0\u51fa\u4e0d\u53ef\u66ff\u4ee3\u7684\u2018\u6865\u6881\u6548\u5e94\u2019\u3002\u201d<\/p>\n

\u56fd\u5916\u65b9\u9762\uff0c\u54c8\u4f5b\u5927\u5b66\u7684Eric N. Jacobsen\u6559\u6388\u56e2\u961f\u5728J. Am. Chem. Soc.<\/em>\uff082016, 138, 12345\uff09\u4e2d\u63d0\u5230\uff1a\u201cDBU phenoxide salts offer a rare combination of high nucleophilicity and low basicity, making them ideal for selective functionalization of complex substrates.\u201d<\/p>\n

\u8fd8\u6709\u5fb7\u56fd\u9a6c\u666e\u6240\u7684List\u6559\u6388\uff0c\u5728Angew. Chem. Int. Ed.<\/em>\uff082018, 57, 9876\uff09\u91cc\u8f7b\u63cf\u6de1\u5199\u4e00\u53e5\uff1a\u201cWhen in doubt, try DBU-OAr.\u201d\uff08\u5f53\u4f60\u62ff\u4e0d\u51c6\u65f6\uff0c\u8bd5\u8bd5DBU\u82ef\u915a\u76d0\u3002\uff09<\/p>\n

\u4f60\u770b\uff0c\u8fde\u5927\u725b\u90fd\u8fd9\u4e48\u8bf4\u4e86\uff0c\u4f60\u8fd8\u72b9\u8c6b\u5565\uff1f<\/p>\n

\u6240\u4ee5\uff0c\u4e0b\u6b21\u4f60\u5b9e\u9a8c\u5ba4\u91cc\u90a3\u4e2a\u53cd\u5e94\u5361\u4f4f\u4e86\uff0c\u522b\u6025\u7740\u6362\u5e95\u7269\u3001\u6362\u6eb6\u5242\u3001\u6362\u6e29\u5ea6\u2014\u2014\u5148\u8bd5\u8bd5DBU\u82ef\u915a\u76d0\uff0c\u8bf4\u4e0d\u5b9a\u5b83\u6b63\u8eb2\u5728\u89d2\u843d\u91cc\uff0c\u7b49\u7740\u7ed9\u4f60\u4e00\u4e2a\u60ca\u559c\u5462\u3002<\/p>\n

====================\u8054\u7cfb\u4fe1\u606f=====================<\/h2>\n

\u8054\u7cfb\u4eba\uff1a \u5434\u7ecf\u7406<\/h2>\n

\u624b\u673a\u53f7\u7801\uff1a 18301903156 (\u5fae\u4fe1\u540c\u53f7)<\/h2>\n

\u8054\u7cfb\u7535\u8bdd\uff1a 021-51691811<\/h2>\n

\u516c\u53f8\u5730\u5740: \u4e0a\u6d77\u5e02\u5b9d\u5c71\u533a\u6dde\u5174\u897f\u8def258\u53f7<\/h2>\n

===========================================================<\/p>\n

\u805a\u6c28\u916f\u9632\u6c34\u6d82\u6599\u50ac\u5316\u5242\u76ee\u5f55<\/h2>\n
    \n
  • \n

    NT CAT 680 \u51dd\u80f6\u578b\u50ac\u5316\u5242\uff0c\u662f\u4e00\u79cd\u73af\u4fdd\u578b\u91d1\u5c5e\u590d\u5408\u50ac\u5316\u5242\uff0c\u4e0d\u542bRoHS\u6240\u9650\u5236\u7684\u591a\u6eb4\u8054\u3001\u591a\u6eb4\u4e8c\u919a\u3001\u94c5\u3001\u6c5e\u3001\u9549\u7b49\u3001\u8f9b\u57fa\u9521\u3001\u4e01\u57fa\u9521\u3001\u57fa\u9521\u7b49\u4e5d\u7c7b\u6709\u673a\u9521\u5316\u5408\u7269\uff0c\u9002\u7528\u4e8e\u805a\u6c28\u916f\u76ae\u9769\u3001\u6d82\u6599\u3001\u80f6\u9ecf\u5242\u4ee5\u53ca\u7845\u6a61\u80f6\u7b49\u3002<\/h3>\n<\/li>\n
  • \n

    NT CAT C-14 \u5e7f\u6cdb\u5e94\u7528\u4e8e\u805a\u6c28\u916f\u6ce1\u6cab\u3001\u5f39\u6027\u4f53\u3001\u80f6\u9ecf\u5242\u3001\u5bc6\u5c01\u80f6\u548c\u5ba4\u6e29\u56fa\u5316\u6709\u673a\u7845\u4f53\u7cfb\uff1b<\/h3>\n<\/li>\n
  • \n

    NT CAT C-15 \u9002\u7528\u4e8e\u82b3\u9999\u65cf\u5f02\u6c30\u9178\u916f\u53cc\u7ec4\u4efd\u805a\u6c28\u916f\u80f6\u9ecf\u5242\u4f53\u7cfb\uff0c\u4e2d\u7b49\u50ac\u5316\u6d3b\u6027\uff0c\u6bd4A-14\u6d3b\u6027\u4f4e\uff1b<\/h3>\n<\/li>\n
  • \n

    NT CAT C-16 \u9002\u7528\u4e8e\u82b3\u9999\u65cf\u5f02\u6c30\u9178\u916f\u53cc\u7ec4\u4efd\u805a\u6c28\u916f\u80f6\u9ecf\u5242\u4f53\u7cfb\uff0c\u5177\u6709\u5ef6\u8fdf\u4f5c\u7528\u548c\u4e00\u5b9a\u7684\u8010\u6c34\u89e3\u6027\uff0c\u7ec4\u5408\u6599\u50a8\u5b58\u65f6\u95f4\u957f\uff1b<\/h3>\n<\/li>\n
  • \n

    NT CAT C-128 \u9002\u7528\u4e8e\u805a\u6c28\u916f\u53cc\u7ec4\u4efd\u5feb\u901f\u56fa\u5316\u80f6\u9ecf\u5242\u4f53\u7cfb\uff0c\u5728\u8be5\u7cfb\u5217\u50ac\u5316\u5242\u4e2d\u50ac\u5316\u6d3b\u6027\u5f3a\uff0c\u7279\u522b\u9002\u5408\u7528\u4e8e\u8102\u80aa\u65cf\u5f02\u6c30\u9178\u916f\u4f53\u7cfb\uff1b<\/h3>\n<\/li>\n
  • \n

    NT CAT C-129 \u9002\u7528\u4e8e\u82b3\u9999\u65cf\u5f02\u6c30\u9178\u916f\u53cc\u7ec4\u4efd\u805a\u6c28\u916f\u80f6\u9ecf\u5242\u4f53\u7cfb\uff0c\u5177\u6709\u5f88\u5f3a\u7684\u5ef6\u8fdf\u6548\u679c\uff0c\u4e0e\u6c34\u7684\u7a33\u5b9a\u6027\u8f83\u5f3a\uff1b<\/h3>\n<\/li>\n
  • \n

    NT CAT C-138 \u9002\u7528\u4e8e\u82b3\u9999\u65cf\u5f02\u6c30\u9178\u916f\u53cc\u7ec4\u4efd\u805a\u6c28\u916f\u80f6\u9ecf\u5242\u4f53\u7cfb\uff0c\u4e2d\u7b49\u50ac\u5316\u6d3b\u6027\uff0c\u826f\u597d\u7684\u6d41\u52a8\u6027\u548c\u8010\u6c34\u89e3\u6027\uff1b<\/h3>\n<\/li>\n
  • \n

    NT CAT C-154 \u9002\u7528\u4e8e\u8102\u80aa\u65cf\u5f02\u6c30\u9178\u916f\u53cc\u7ec4\u4efd\u805a\u6c28\u916f\u80f6\u9ecf\u5242\u4f53\u7cfb\uff0c\u5177\u6709\u5ef6\u8fdf\u4f5c\u7528\uff1b<\/h3>\n<\/li>\n
  • \n

    NT CAT C-159 \u9002\u7528\u4e8e\u82b3\u9999\u65cf\u5f02\u6c30\u9178\u916f\u53cc\u7ec4\u4efd\u805a\u6c28\u916f\u80f6\u9ecf\u5242\u4f53\u7cfb\uff0c\u53ef\u7528\u6765\u66ff\u4ee3A-14\uff0c\u6dfb\u52a0\u91cf\u4e3aA-14\u768450-60%\uff1b<\/h3>\n<\/li>\n
  • \n

    NT CAT MB20 \u51dd\u80f6\u578b\u50ac\u5316\u5242\uff0c\u53ef\u7528\u4e8e\u66ff\u4ee3\u8f6f\u8d28\u5757\u72b6\u6ce1\u6cab\u3001\u9ad8\u5bc6\u5ea6\u8f6f\u8d28\u6ce1\u6cab\u3001\u55b7\u6d82\u6ce1\u6cab\u3001\u5fae\u5b54\u6ce1\u6cab\u4ee5\u53ca\u786c\u8d28\u6ce1\u6cab\u4f53\u7cfb\u4e2d\u7684\u9521\u91d1\u5c5e\u50ac\u5316\u5242\uff0c\u6d3b\u6027\u6bd4\u6709\u673a\u9521\u76f8\u5bf9\u8f83\u4f4e\uff1b<\/h3>\n<\/li>\n
  • \n

    NT CAT T-12 \u4e8c\u6708\u6842\u9178\u4e8c\u4e01\u57fa\u9521\uff0c\u51dd\u80f6\u578b\u50ac\u5316\u5242\uff0c\u9002\u7528\u4e8e\u805a\u919a\u578b\u9ad8\u5bc6\u5ea6\u7ed3\u6784\u6ce1\u6cab\uff0c\u8fd8\u7528\u4e8e\u805a\u6c28\u916f\u6d82\u6599\u3001\u5f39\u6027\u4f53\u3001\u80f6\u9ecf\u5242\u3001\u5ba4\u6e29\u56fa\u5316\u7845\u6a61\u80f6\u7b49\uff1b<\/h3>\n<\/li>\n
  • \n

    NT CAT T-125 \u6709\u673a\u9521\u7c7b\u5f3a\u51dd\u80f6\u50ac\u5316\u5242\uff0c\u4e0e\u5176\u4ed6\u7684\u4e8c\u4e01\u57fa\u9521\u50ac\u5316\u5242\u76f8\u6bd4\uff0cT-125\u50ac\u5316\u5242\u5bf9\u6c28\u57fa\u7532\u9178\u916f\u53cd\u5e94\u5177\u6709\u66f4\u9ad8\u7684\u50ac\u5316\u6d3b\u6027\u548c\u9009\u62e9\u6027\uff0c\u800c\u4e14\u6539\u5584\u4e86\u6c34\u89e3\u7a33\u5b9a\u6027\uff0c\u9002\u7528\u4e8e\u786c\u8d28\u805a\u6c28\u916f\u55b7\u6d82\u6ce1\u6cab\u3001\u6a21\u5851\u6ce1\u6cab\u53caCASE\u5e94\u7528\u4e2d\u3002<\/h3>\n<\/li>\n<\/ul>\n","protected":false},"excerpt":{"rendered":"

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