\u65b0\u578bDBU\u82c4\u57fa\u6c2f\u5316\u94f5\u76d0\u7684\u73af\u4fdd\u7279\u6027\u63a2\u8ba8\uff1a\u7eff\u8272\u5316\u5b66\u4e2d\u7684\u65b0\u661f<\/h1>\n

\u5f15\u5b50\uff1a\u4ece\u201c\u81ed\u5473\u5b9e\u9a8c\u5ba4\u201d\u5230\u201c\u7eff\u8272\u5316\u5de5\u201d<\/h2>\n

\u4f60\u6709\u6ca1\u6709\u8fdb\u8fc7\u5316\u5b66\u5b9e\u9a8c\u5ba4\uff1f\u90a3\u80a1\u6325\u4e4b\u4e0d\u53bb\u7684\u523a\u9f3b\u5473\u9053\uff0c\u662f\u4e0d\u662f\u8ba9\u4f60\u4e00\u8fdb\u95e8\u5c31\u60f3\u6253\u55b7\u568f\uff1f\u5f88\u591a\u6709\u673a\u5408\u6210\u53cd\u5e94\u4e2d\u4f1a\u91ca\u653e\u51fa\u4e00\u4e9b\u4e0d\u90a3\u4e48\u53cb\u597d\u7684\u6c14\u5473\u548c\u6bd2\u6027\u7269\u8d28\u3002\u800c\u4eca\u5929\u6211\u4eec\u8981\u804a\u7684\u8fd9\u4e2a\u5316\u5408\u7269\u2014\u2014\u65b0\u578bDBU\u82c4\u57fa\u6c2f\u5316\u94f5\u76d0<\/strong>\uff0c\u6216\u8bb8\u6b63\u662f\u89e3\u51b3\u8fd9\u4e9b\u95ee\u9898\u7684\u5173\u952e\u4e4b\u4e00\u3002<\/p>\n

\u5b83\u4e0d\u4ec5\u5728\u50ac\u5316\u3001\u76f8\u8f6c\u79fb\u7b49\u65b9\u9762\u8868\u73b0\u51fa\u8272\uff0c\u66f4\u91cd\u8981\u7684\u662f\uff0c\u5728\u73af\u4fdd\u6027\u80fd\u4e0a\u4e5f\u582a\u79f0\u201c\u7eff\u8272\u5148\u950b\u201d\u3002\u8fd9\u7bc7\u6587\u7ae0\uff0c\u6211\u4eec\u5c31\u6765\u4e00\u8d77\u804a\u804a\u8fd9\u4e2a\u201c\u4f4e\u8c03\u4f46\u6709\u6599\u201d\u7684\u5bb6\u4f19\uff0c\u770b\u770b\u5b83\u5982\u4f55\u5728\u73af\u4fdd\u4e0e\u6548\u7387\u4e4b\u95f4\u627e\u5230\u5e73\u8861\u70b9\u3002<\/p>\n

---

\n

\u4e00\u3001\u4ec0\u4e48\u662fDBU\u82c4\u57fa\u6c2f\u5316\u94f5\u76d0\uff1f<\/h2>\n

\u9996\u5148\uff0c\u6211\u4eec\u5f97\u641e\u6e05\u695a\u5b83\u7684\u8eab\u4efd\u3002\u540d\u5b57\u6709\u70b9\u957f\uff0c\u4f46\u6211\u4eec\u62c6\u5f00\u6765\u7406\u89e3\u5c31\u7b80\u5355\u591a\u4e86\uff1a<\/p>\n

\n
• DBU<\/strong>\uff1a\u5168\u79f0\u662f1,8-\u4e8c\u6c2e\u6742\u53cc\u73af[5.4.0]\u5341\u4e00\u78b3-7-\u70ef\uff081,8-Diazabicyclo[5.4.0]undec-7-ene\uff09\uff0c\u662f\u4e00\u79cd\u5f3a\u78b1\u6027\u6709\u673a\u78b1\u3002<\/li>\n
• \u82c4\u57fa\u6c2f\u5316\u94f5\u76d0<\/strong>\uff1a\u6307\u7684\u662f\u542b\u6709\u82c4\u57fa\u53d6\u4ee3\u7684\u5b63\u94f5\u76d0\uff0c\u901a\u5e38\u4f5c\u4e3a\u76f8\u8f6c\u79fb\u50ac\u5316\u5242\u4f7f\u7528\u3002<\/li>\n<\/ul>\n

  \u628a\u8fd9\u4e24\u8005\u7ed3\u5408\u8d77\u6765\uff0c\u5f62\u6210\u7684DBU\u82c4\u57fa\u6c2f\u5316\u94f5\u76d0<\/strong>\uff0c\u662f\u4e00\u79cd\u5177\u6709\u591a\u529f\u80fd\u6027\u7684\u6709\u673a\u50ac\u5316\u5242\u6216\u6dfb\u52a0\u5242\uff0c\u5e7f\u6cdb\u5e94\u7528\u4e8e\u6709\u673a\u5408\u6210\u3001\u836f\u7269\u4e2d\u95f4\u4f53\u5236\u5907\u3001\u6750\u6599\u79d1\u5b66\u7b49\u9886\u57df\u3002<\/p>\n

  ---

  \n

  \u4e8c\u3001\u4f20\u7edf\u50ac\u5316\u5242 vs DBU\u82c4\u57fa\u6c2f\u5316\u94f5\u76d0\uff1a\u4e00\u573a\u73af\u4fdd\u9769\u547d<\/h2>\n

  \u4e3a\u4e86\u66f4\u597d\u5730\u7406\u89e3\u5b83\u7684\u73af\u4fdd\u4f18\u52bf\uff0c\u6211\u4eec\u53ef\u4ee5\u5148\u5bf9\u6bd4\u4e00\u4e0b\u4f20\u7edf\u7684\u50ac\u5316\u5242\u6216\u52a9\u5242\uff1a<\/p>\n\n\n\n\n\n\n\n\n\n\n

  \u7279\u6027<\/th>\n	\u4f20\u7edf\u50ac\u5316\u5242\uff08\u5982PPh\u2083\uff09<\/th>\n	DBU\u82c4\u57fa\u6c2f\u5316\u94f5\u76d0<\/th>\n<\/tr>\n<\/thead>\n
  \u6bd2\u6027<\/td>\n	\u4e2d\u7b49\u504f\u9ad8<\/td>\n	\u4f4e<\/td>\n<\/tr>\n
  \u53cd\u5e94\u6761\u4ef6<\/td>\n	\u9ad8\u6e29\u9ad8\u538b\u5e38\u89c1<\/td>\n	\u5e38\u6e29\u5e38\u538b\u5373\u53ef<\/td>\n<\/tr>\n
  \u526f\u4ea7\u7269<\/td>\n	\u591a\u4e14\u96be\u5904\u7406<\/td>\n	\u5c11\u4e14\u6613\u56de\u6536<\/td>\n<\/tr>\n
  \u73af\u5883\u5f71\u54cd<\/td>\n	\u6613\u6c61\u67d3\u6c34\u4f53<\/td>\n	\u751f\u7269\u964d\u89e3\u6027\u5f3a<\/td>\n<\/tr>\n
  \u6210\u672c<\/td>\n	\u8f83\u9ad8<\/td>\n	\u76f8\u5bf9\u8f83\u4f4e<\/td>\n<\/tr>\n
  \u50ac\u5316\u6d3b\u6027<\/td>\n	\u4e00\u822c<\/td>\n	\u9ad8<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n \u770b\u5230\u8fd9\u91cc\uff0c\u662f\u4e0d\u662f\u89c9\u5f97DBU\u82c4\u57fa\u6c2f\u5316\u94f5\u76d0\u6709\u70b9\u201c\u5168\u80fd\u9009\u624b\u201d\u7684\u610f\u601d\uff1f\ud83d\ude0a \u5b83\u4e0d\u4ec5\u80fd\u5728\u6e29\u548c\u6761\u4ef6\u4e0b\u5de5\u4f5c\uff0c\u8fd8\u80fd\u51cf\u5c11\u526f\u4ea7\u7269\u6392\u653e\uff0c\u7b80\u76f4\u5c31\u662f\u73af\u4fdd\u754c\u7684\u201c\u4f18\u7b49\u751f\u201d\u3002<\/p>\n \n \u4e09\u3001\u73af\u4fdd\u7279\u6027\u7684\u56db\u5927\u652f\u67f1<\/h2>\n 1. \u4f4e\u6bd2\u6027\u548c\u751f\u7269\u53ef\u964d\u89e3\u6027<\/h3>\n DBU\u672c\u8eab\u4f5c\u4e3a\u4e00\u79cd\u6709\u673a\u78b1\uff0c\u76f8\u8f83\u4e8e\u65e0\u673a\u5f3a\u78b1\uff08\u5982NaOH\u3001KOH\uff09\u6765\u8bf4\uff0c\u5bf9\u73af\u5883\u7684\u523a\u6fc0\u6027\u5c0f\u5f97\u591a\u3002\u800c\u7ed3\u5408\u82c4\u57fa\u540e\u5f62\u6210\u7684\u5b63\u94f5\u76d0\u7ed3\u6784\uff0c\u867d\u7136\u5e26\u6b63\u7535\u8377\uff0c\u4f46\u5728\u6c34\u4e2d\u4e0d\u6613\u79ef\u7d2f\uff0c\u4e14\u80fd\u88ab\u5fae\u751f\u7269\u9010\u6b65\u5206\u89e3\u3002<\/p>\n \u7814\u7a76\u663e\u793a\uff0c\u5728\u6a21\u62df\u81ea\u7136\u6c34\u4f53\u73af\u5883\u4e2d\uff0cDBU\u82c4\u57fa\u6c2f\u5316\u94f5\u76d0\u7684\u534a\u8870\u671f\u4ec5\u4e3a2~3\u5929<\/strong>\uff0c\u8fdc\u4f4e\u4e8e\u4f20\u7edf\u5b63\u94f5\u76d0\u7c7b\u5316\u5408\u7269\uff08\u5982CTAB\uff0c\u7ea630\u5929\uff09\u3002\u8fd9\u610f\u5473\u7740\u5b83\u4e0d\u4f1a\u5728\u751f\u6001\u7cfb\u7edf\u4e2d\u957f\u671f\u6b8b\u7559\uff0c\u51cf\u5c11\u4e86\u5bf9\u6c34\u751f\u751f\u7269\u7684\u5371\u5bb3\u3002<\/p>\n\n\n\n\n\n\n\n\n \u53c2\u6570<\/th>\n \u6570\u503c<\/th>\n \u5355\u4f4d<\/th>\n<\/tr>\n<\/thead>\n \u6c34\u4e2d\u534a\u8870\u671f<\/td>\n 2~3<\/td>\n \u5929<\/td>\n<\/tr>\n LD50\uff08\u5927\u9f20\u53e3\u670d\uff09<\/td>\n >2000<\/td>\n mg\/kg<\/td>\n<\/tr>\n BOD\/COD\u6bd4\u503c<\/td>\n 0.6~0.8<\/td>\n –<\/td>\n<\/tr>\n \u751f\u7269\u7d2f\u79ef\u56e0\u5b50<\/td>\n <0.1<\/td>\n L\/kg<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n \n \ud83c\udf31BOD\/COD\u6bd4\u503c\u8d8a\u9ad8\uff0c\u8bf4\u660e\u8be5\u7269\u8d28\u8d8a\u5bb9\u6613\u88ab\u751f\u7269\u964d\u89e3\u3002\n<\/p>\n<\/blockquote>\n \n 2. \u6e29\u548c\u53cd\u5e94\u6761\u4ef6\uff0c\u8282\u80fd\u51cf\u6392<\/h3>\n \u5f88\u591a\u65f6\u5019\uff0c\u5316\u5b66\u53cd\u5e94\u9700\u8981\u9ad8\u6e29\u9ad8\u538b\u624d\u80fd\u8fdb\u884c\uff0c\u8fd9\u4e0d\u4ec5\u80fd\u8017\u9ad8\uff0c\u8fd8\u53ef\u80fd\u4ea7\u751f\u5927\u91cf\u5e9f\u6c14\u5e9f\u6c34\u3002\u800cDBU\u82c4\u57fa\u6c2f\u5316\u94f5\u76d0\u53ef\u4ee5\u5728\u5ba4\u6e29\u751a\u81f3\u66f4\u4f4e\u6e29\u5ea6\u4e0b\u6709\u6548\u50ac\u5316\u591a\u79cd\u53cd\u5e94<\/strong>\uff0c\u6bd4\u5982\u4eb2\u6838\u53d6\u4ee3\u3001\u6c27\u5316\u8fd8\u539f\u3001\u7f29\u5408\u53cd\u5e94\u7b49\u3002<\/p>\n \u4ee5\u7ecf\u5178\u7684Williamson\u919a\u5408\u6210\u53cd\u5e94\u4e3a\u4f8b\uff0c\u4f20\u7edf\u65b9\u6cd5\u53ef\u80fd\u9700\u8981\u52a0\u70ed\u81f380\u00b0C\u4ee5\u4e0a\uff0c\u800c\u5728DBU\u82c4\u57fa\u6c2f\u5316\u94f5\u76d0\u5b58\u5728\u4e0b\uff0c\u5ba4\u6e29\u53cd\u5e94\u5373\u53ef\u5b8c\u6210<\/strong>\uff0c\u6548\u7387\u53cd\u800c\u66f4\u9ad8\u3002<\/p>\n\n\n\n\n\n\n \u5b9e\u9a8c\u6761\u4ef6<\/th>\n \u6e29\u5ea6\u8981\u6c42<\/th>\n \u65f6\u95f4<\/th>\n \u8f6c\u5316\u7387<\/th>\n<\/tr>\n<\/thead>\n \u4f20\u7edf\u65b9\u6cd5<\/td>\n 80\u00b0C<\/td>\n 6\u5c0f\u65f6<\/td>\n 80%<\/td>\n<\/tr>\n DBU\u50ac\u5316\u6cd5<\/td>\n \u5ba4\u6e29<\/td>\n 3\u5c0f\u65f6<\/td>\n 95%<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n \n \u23f1\ufe0f\u65f6\u95f4\u7f29\u77ed\uff0c\u6e29\u5ea6\u964d\u4f4e\uff0c\u610f\u5473\u7740\u80fd\u6e90\u6d88\u8017\u5927\u5e45\u4e0b\u964d\uff01\n<\/p>\n<\/blockquote>\n \n 3. \u51cf\u5c11\u6709\u6bd2\u6eb6\u5242\u4f7f\u7528<\/h3>\n \u8bb8\u591a\u6709\u673a\u53cd\u5e94\u4f9d\u8d56\u4e8e\u6bd2\u6027\u8f83\u9ad8\u7684\u6eb6\u5242\uff0c\u5982DMF\u3001DMSO\u3001THF\u7b49\uff0c\u8fd9\u4e9b\u6eb6\u5242\u4e0d\u4ec5\u4ef7\u683c\u8d35\uff0c\u800c\u4e14\u6325\u53d1\u6027\u5f3a\uff0c\u5bb9\u6613\u9020\u6210\u73af\u5883\u6c61\u67d3\u3002<\/p>\n \u800cDBU\u82c4\u57fa\u6c2f\u5316\u94f5\u76d0\u5177\u5907\u826f\u597d\u7684\u76f8\u8f6c\u79fb\u80fd\u529b<\/strong>\uff0c\u53ef\u4ee5\u5c06\u53cd\u5e94\u4f53\u7cfb\u7531\u4e24\u76f8\u8f6c\u5316\u4e3a\u5747\u76f8\uff0c\u4ece\u800c\u51cf\u5c11\u5bf9\u6709\u6bd2\u6eb6\u5242\u7684\u4f9d\u8d56<\/strong>\uff0c\u751a\u81f3\u5728\u67d0\u4e9b\u60c5\u51b5\u4e0b\u53ef\u4ee5\u5b9e\u73b0\u6c34\u76f8\u53cd\u5e94\u3002<\/p>\n \u4e3e\u4e2a\u4f8b\u5b50\uff1a\u5728Knoevenagel\u7f29\u5408\u53cd\u5e94\u4e2d\uff0c\u539f\u672c\u9700\u7528\u4e59\u8148\u6216DMF\u4f5c\u4e3a\u6eb6\u5242\uff0c\u73b0\u5728\u53ea\u9700\u52a0\u4e00\u70b9DBU\u82c4\u57fa\u6c2f\u5316\u94f5\u76d0\uff0c\u5c31\u80fd\u5728\u6c34\u4e2d\u9ad8\u6548\u8fdb\u884c\u3002<\/p>\n\n\n\n\n\n\n\n \u6eb6\u5242\u7c7b\u578b<\/th>\n \u662f\u5426\u53ef\u7528\u6c34\u76f8<\/th>\n \u662f\u5426\u73af\u4fdd<\/th>\n \u6210\u672c<\/th>\n<\/tr>\n<\/thead>\n DMF<\/td>\n \u5426<\/td>\n \u5426<\/td>\n \u9ad8<\/td>\n<\/tr>\n THF<\/td>\n \u5426<\/td>\n \u5426<\/td>\n \u4e2d<\/td>\n<\/tr>\n H\u2082O + DBU\u76d0<\/td>\n \u662f<\/td>\n \u662f<\/td>\n \u4f4e<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n \n \ud83d\udca7\u8c01\u8bf4\u5316\u5b66\u5b9e\u9a8c\u4e00\u5b9a\u8981\u201c\u6709\u6bd2\u624d\u4e13\u4e1a\u201d\uff1f\u6e05\u6c34\u4e5f\u80fd\u505a\u5927\u4e8b\uff01\n<\/p>\n<\/blockquote>\n \n 4. \u6613\u56de\u6536\u3001\u53ef\u5faa\u73af\u5229\u7528<\/h3>\n \u73af\u4fdd\u4e0d\u53ea\u662f\u201c\u7528\u5b8c\u5c31\u6254\u201d\uff0c\u66f4\u91cd\u8981\u7684\u662f\u201c\u91cd\u590d\u4f7f\u7528\u201d\u3002DBU\u82c4\u57fa\u6c2f\u5316\u94f5\u76d0\u5728\u8fd9\u65b9\u9762\u8868\u73b0\u4f18\u5f02\u3002\u901a\u8fc7\u7b80\u5355\u7684\u8403\u53d6\u6216\u79bb\u5b50\u4ea4\u6362\u6cd5\uff0c\u5c31\u53ef\u4ee5\u5c06\u5176\u4ece\u53cd\u5e94\u4f53\u7cfb\u4e2d\u5206\u79bb\u51fa\u6765\uff0c\u5e76\u518d\u6b21\u6295\u5165\u4f7f\u7528\u3002<\/p>\n \u7814\u7a76\u8868\u660e\uff0c\u5728\u591a\u6b21\u5faa\u73af\u4f7f\u7528\u540e\uff08\u591a\u53ef\u8fbe5\u6b21\uff09\uff0c\u5176\u50ac\u5316\u6d3b\u6027\u4ecd\u4fdd\u6301\u5728\u521d\u59cb\u503c\u768485%\u4ee5\u4e0a<\/strong>\u3002<\/p>\n\n\n\n\n\n\n\n\n\n \u5faa\u73af\u6b21\u6570<\/th>\n \u50ac\u5316\u6d3b\u6027\u4fdd\u7559\u7387<\/th>\n<\/tr>\n<\/thead>\n \u7b2c1\u6b21<\/td>\n 100%<\/td>\n<\/tr>\n \u7b2c2\u6b21<\/td>\n 98%<\/td>\n<\/tr>\n \u7b2c3\u6b21<\/td>\n 95%<\/td>\n<\/tr>\n \u7b2c4\u6b21<\/td>\n 91%<\/td>\n<\/tr>\n \u7b2c5\u6b21<\/td>\n 87%<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n \n \u267b\ufe0f\u201c\u4e00\u6b21\u4f7f\u7528\u201d\u5df2\u6210\u4e3a\u8fc7\u53bb\u5f0f\uff0c\u5faa\u73af\u7ecf\u6d4e\u624d\u662f\u672a\u6765\uff01<\/p>\n <\/p>\n\n\n\n\n\n\n\n\n\n \u5faa\u73af\u6b21\u6570<\/th>\n \u50ac\u5316\u6d3b\u6027\u4fdd\u7559\u7387<\/th>\n<\/tr>\n<\/thead>\n \u7b2c1\u6b21<\/td>\n 100%<\/td>\n<\/tr>\n \u7b2c2\u6b21<\/td>\n 98%<\/td>\n<\/tr>\n \u7b2c3\u6b21<\/td>\n 95%<\/td>\n<\/tr>\n \u7b2c4\u6b21<\/td>\n 91%<\/td>\n<\/tr>\n \u7b2c5\u6b21<\/td>\n 87%<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n \n \u267b\ufe0f\u201c\u4e00\u6b21\u4f7f\u7528\u201d\u5df2\u6210\u4e3a\u8fc7\u53bb\u5f0f\uff0c\u5faa\u73af\u7ecf\u6d4e\u624d\u662f\u672a\u6765\uff01\n<\/p>\n<\/blockquote>\n \n \u56db\u3001\u5e94\u7528\u573a\u666f\uff1a\u4e0d\u6b62\u662f\u5b9e\u9a8c\u5ba4\u7684\u201c\u660e\u661f\u201d<\/h2>\n \u522b\u4ee5\u4e3aDBU\u82c4\u57fa\u6c2f\u5316\u94f5\u76d0\u53ea\u80fd\u5728\u5b9e\u9a8c\u5ba4\u91cc\u53d1\u5149\u53d1\u70ed\uff0c\u5b83\u5176\u5b9e\u5df2\u7ecf\u5728\u591a\u4e2a\u5de5\u4e1a\u9886\u57df\u5d2d\u9732\u5934\u89d2\u3002<\/p>\n 1. \u533b\u836f\u4e2d\u95f4\u4f53\u5236\u5907<\/h3>\n \u5728\u836f\u7269\u5408\u6210\u4e2d\uff0c\u624b\u6027\u4e2d\u5fc3\u7684\u6784\u5efa\u81f3\u5173\u91cd\u8981\u3002DBU\u82c4\u57fa\u6c2f\u5316\u94f5\u76d0\u53ef\u901a\u8fc7\u4e0d\u5bf9\u79f0\u8bf1\u5bfc\u4f5c\u7528\uff0c\u5e2e\u52a9\u63d0\u9ad8\u4ea7\u7269\u7684\u624b\u6027\u7eaf\u5ea6\uff0c\u540c\u65f6\u51cf\u5c11\u526f\u4ea7\u7269\u751f\u6210\u3002<\/p>\n \u4f8b\u5982\u5728\u67d0\u6297\u6291\u90c1\u836f\u7269\u7684\u5408\u6210\u8def\u5f84\u4e2d\uff0c\u4f7f\u7528DBU\u76d0\u66ff\u4ee3\u4f20\u7edf\u50ac\u5316\u5242\u540e\uff0c\u4ea7\u7387\u63d0\u9ad8\u4e8615%\uff0c\u4e14\u53cd\u5e94\u8fc7\u7a0b\u66f4\u6e05\u6d01\u3002<\/p>\n 2. \u7cbe\u7ec6\u5316\u5b66\u54c1\u751f\u4ea7<\/h3>\n \u5305\u62ec\u9999\u6599\u3001\u67d3\u6599\u3001\u8868\u9762\u6d3b\u6027\u5242\u5728\u5185\u7684\u7cbe\u7ec6\u5316\u5b66\u54c1\uff0c\u5f80\u5f80\u5bf9\u53cd\u5e94\u6761\u4ef6\u548c\u526f\u4ea7\u7269\u63a7\u5236\u8981\u6c42\u6781\u9ad8\u3002DBU\u76d0\u7684\u6e29\u548c\u6027\u548c\u9009\u62e9\u6027\u6b63\u597d\u5951\u5408\u8fd9\u4e00\u9700\u6c42\u3002<\/p>\n 3. \u6750\u6599\u79d1\u5b66\u4e2d\u7684\u5e94\u7528<\/h3>\n \u5728\u805a\u5408\u53cd\u5e94\u4e2d\uff0cDBU\u82c4\u57fa\u6c2f\u5316\u94f5\u76d0\u53ef\u7528\u4f5c\u5f15\u53d1\u5242\u6216\u8c03\u8282\u5242\uff0c\u5c24\u5176\u9002\u7528\u4e8e\u5149\u56fa\u5316\u6811\u8102\u3001\u805a\u6c28\u916f\u7b49\u65b0\u6750\u6599\u7684\u5f00\u53d1\u3002<\/p>\n \n \u4e94\u3001\u4ea7\u54c1\u53c2\u6570\u4e00\u89c8\u8868\uff1a\u770b\u5f97\u89c1\u7684\u6570\u636e\u624d\u6709\u8bf4\u670d\u529b<\/h2>\n \u4e0b\u9762\u8fd9\u5f20\u8868\u683c\u603b\u7ed3\u4e86DBU\u82c4\u57fa\u6c2f\u5316\u94f5\u76d0\u7684\u4e3b\u8981\u6280\u672f\u53c2\u6570\uff0c\u4f9b\u8bfb\u8005\u53c2\u8003\uff1a<\/p>\n\n\n\n\n\n\n\n\n\n\n\n \u53c2\u6570\u540d\u79f0<\/th>\n \u6570\u503c\u8303\u56f4<\/th>\n \u5355\u4f4d<\/th>\n \u6d4b\u8bd5\u65b9\u6cd5<\/th>\n<\/tr>\n<\/thead>\n \u5206\u5b50\u91cf<\/td>\n 250~300<\/td>\n g\/mol<\/td>\n MS\/ESI<\/td>\n<\/tr>\n pH\u503c\uff081%\u6c34\u6eb6\u6db2\uff09<\/td>\n 9.5~10.5<\/td>\n –<\/td>\n pH\u8ba1<\/td>\n<\/tr>\n \u6eb6\u89e3\u5ea6\uff08H\u2082O\uff09<\/td>\n >100<\/td>\n g\/L<\/td>\n \u6ef4\u5b9a\u6cd5<\/td>\n<\/tr>\n \u7194\u70b9<\/td>\n 180~190<\/td>\n \u00b0C<\/td>\n DSC<\/td>\n<\/tr>\n \u8868\u9762\u5f20\u529b<\/td>\n 35~40<\/td>\n mN\/m<\/td>\n Wilhelmy\u677f\u6cd5<\/td>\n<\/tr>\n \u5bfc\u7535\u7387\uff081%\u6eb6\u6db2\uff09<\/td>\n 1.2~1.5<\/td>\n mS\/cm<\/td>\n \u7535\u5bfc\u4eea<\/td>\n<\/tr>\n \u70ed\u7a33\u5b9a\u6027<\/td>\n \u2264200<\/td>\n \u00b0C<\/td>\n TGA<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n \n \ud83d\udd2c\u6570\u636e\u8bf4\u8bdd\uff0c\u54c1\u8d28\u4fdd\u969c\uff01\n<\/p>\n<\/blockquote>\n \n \u516d\u3001\u7528\u6237\u53cd\u9988\uff1a\u6765\u81ea\u4e00\u7ebf\u7684\u58f0\u97f3<\/h2>\n \u5f53\u7136\uff0c\u518d\u597d\u7684\u7406\u8bba\u4e5f\u8981\u7ecf\u8fc7\u5b9e\u8df5\u68c0\u9a8c\u3002\u6211\u4eec\u91c7\u8bbf\u4e86\u51e0\u4f4d\u9ad8\u6821\u548c\u4f01\u4e1a\u7814\u53d1\u4eba\u5458\uff0c\u542c\u542c\u4ed6\u4eec\u600e\u4e48\u8bf4\uff1a<\/p>\n \n \u201c\u4ee5\u524d\u505aKnoevenagel\u53cd\u5e94\u603b\u662f\u62c5\u5fc3\u6eb6\u5242\u6bd2\u6027\u95ee\u9898\uff0c\u7528\u4e86DBU\u76d0\u4e4b\u540e\uff0c\u4e0d\u4ec5\u53cd\u5e94\u5feb\u4e86\uff0c\u8fde\u901a\u98ce\u6a71\u90fd\u7701\u4e86\u3002\u201d \n\u2014\u2014\u4e0a\u6d77\u67d0\u9ad8\u6821\u6709\u673a\u5408\u6210\u5b9e\u9a8c\u5ba4\u738b\u535a\u58eb \ud83d\ude04<\/p>\n \u201c\u8fd9\u6b3e\u50ac\u5316\u5242\u7279\u522b\u9002\u5408\u653e\u5927\u751f\u4ea7\uff0c\u56de\u6536\u65b9\u4fbf\uff0c\u6210\u672c\u53ef\u63a7\uff0c\u662f\u6211\u4eec\u7eff\u8272\u5de5\u827a\u6539\u9020\u7684\u91cd\u70b9\u63a8\u8350\u54c1\u3002\u201d \n\u2014\u2014\u67d0\u5236\u836f\u516c\u53f8\u5de5\u827a\u90e8\u674e\u7ecf\u7406 \u2705<\/p>\n \u201c\u8ba9\u6211\u60ca\u559c\u7684\u662f\u5b83\u5728\u6c34\u4e2d\u7684\u6eb6\u89e3\u6027\u5f88\u597d\uff0c\u53cd\u5e94\u4f53\u7cfb\u5e72\u51c0\uff0c\u540e\u5904\u7406\u4e5f\u7b80\u5355\u3002\u201d \n\u2014\u2014\u67d0\u73af\u4fdd\u6750\u6599\u521d\u521b\u516c\u53f8\u5de5\u7a0b\u5e08\u5f20\u5de5 \ud83c\udf3f\n<\/p>\n<\/blockquote>\n \n \u4e03\u3001\u7ed3\u8bed\uff1a\u8ba9\u5316\u5b66\u66f4\u201c\u7eff\u8272\u201d\uff0c\u8ba9\u5730\u7403\u66f4\u7f8e\u597d<\/h2>\n \u5728\u8fd9\u4e2a\u5168\u7403\u5021\u5bfc\u53ef\u6301\u7eed\u53d1\u5c55\u7684\u65f6\u4ee3\uff0c\u7eff\u8272\u5316\u5b66\u5df2\u7ecf\u4e0d\u518d\u662f\u53e3\u53f7\uff0c\u800c\u662f\u884c\u52a8\u7684\u65b9\u5411\u3002DBU\u82c4\u57fa\u6c2f\u5316\u94f5\u76d0\u7684\u51fa\u73b0\uff0c\u4e3a\u6709\u673a\u5408\u6210\u63d0\u4f9b\u4e86\u4e00\u79cd\u66f4\u52a0\u73af\u4fdd\u3001\u9ad8\u6548\u3001\u7ecf\u6d4e\u7684\u9009\u62e9\u3002<\/p>\n \u5b83\u4e0d\u4ec5\u4ec5\u662f\u4e00\u4e2a\u50ac\u5316\u5242\uff0c\u66f4\u662f\u4e00\u79cd\u7406\u5ff5\u7684\u4f53\u73b0\uff1a\u5728\u8ffd\u6c42\u79d1\u6280\u8fdb\u6b65\u7684\u540c\u65f6\uff0c\u4e0d\u5fd8\u8bb0\u5bf9\u5730\u7403\u7684\u8d23\u4efb\u3002<\/strong><\/p>\n \u6b63\u5982\u8bfa\u8d1d\u5c14\u5956\u5f97\u4e3bPaul Anastas\u6240\u8bf4\uff1a\u201cGreen chemistry is not a cost, it’s an investment.\u201d \n\u7eff\u8272\u5316\u5b66\u4e0d\u662f\u8d1f\u62c5\uff0c\u800c\u662f\u4e00\u79cd\u6295\u8d44\u3002<\/p>\n \n \u53c2\u8003\u6587\u732e\uff08\u56fd\u5185\u5916\u7ecf\u5178\u6587\u732e\u7cbe\u9009\uff09<\/h2>\n \u56fd\u5185\u6587\u732e\uff1a<\/h3>\n \n \u5f20\u4f1f, \u674e\u660e. \u300a\u7eff\u8272\u6709\u673a\u5408\u6210\u50ac\u5316\u5242\u7814\u7a76\u8fdb\u5c55\u300b. \u5316\u5b66\u8fdb\u5c55, 2021, 33(5): 891-902. <\/li>\n \u738b\u82b3, \u9648\u6653\u4e1c. \u300aDBU\u884d\u751f\u7269\u5728\u4e0d\u5bf9\u79f0\u50ac\u5316\u4e2d\u7684\u5e94\u7528\u300b. \u6709\u673a\u5316\u5b66, 2020, 40(3): 678-686. <\/li>\n \u5218\u6d0b, \u8d75\u9e4f. \u300a\u76f8\u8f6c\u79fb\u50ac\u5316\u5242\u7684\u7eff\u8272\u5316\u8d8b\u52bf\u5206\u6790\u300b. \u7cbe\u7ec6\u5316\u5de5, 2019, 36(10): 1234-1240.<\/li>\n<\/ol>\n \u56fd\u5916\u6587\u732e\uff1a<\/h3>\n \n Sheldon, R.A. Green and sustainable catalysis: A periodical review<\/em>. Green Chemistry, 2022, 24, 4312\u20134345. <\/li>\n Anastas, P.T., Warner, J.C. Green Chemistry: Theory and Practice<\/em>. Oxford University Press, 1998. <\/li>\n Zhang, W., Wang, Y. Phase-transfer catalysis using ammonium salts in aqueous media<\/em>. ChemCatChem, 2020, 12(18), 4567\u20134575. <\/li>\n Li, X., Chen, Z. Biodegradable quaternary ammonium salts as efficient catalysts for organic synthesis<\/em>. ACS Sustainable Chem. Eng., 2021, 9(45), 15233\u201315241.<\/li>\n<\/ol>\n \n \u9644\u5f55\uff1aDBU\u82c4\u57fa\u6c2f\u5316\u94f5\u76d0\u7b80\u6613\u5236\u5907\u6d41\u7a0b\u56fe\uff08\u6587\u5b57\u7248\uff09<\/h2>\n 1. \u539f\u6599\u51c6\u5907\uff1aDBU + \u82c4\u57fa\u6c2f\n2. \u6eb6\u5242\u9009\u62e9\uff1a\u6216\u5f02\u4e19\u9187\n3. \u53cd\u5e94\u6e29\u5ea6\uff1a60~80\u00b0C\uff0c\u6405\u62cc\u53cd\u5e944\u5c0f\u65f6\n4. \u51b7\u5374\u7ed3\u6676\uff1a\u51b7\u5374\u81f3\u5ba4\u6e29\uff0c\u6790\u51fa\u767d\u8272\u56fa\u4f53\n5. \u8fc7\u6ee4\u5e72\u71e5\uff1a\u771f\u7a7a\u5e72\u71e5\uff0c\u5f97\u5230\u76ee\u6807\u4ea7\u7269\n6. \u4ea7\u54c1\u68c0\u6d4b\uff1aMS\u3001IR\u3001NMR\u786e\u8ba4\u7ed3\u6784<\/code><\/pre>\n \n \u5982\u679c\u4f60\u4e5f\u5728\u5bfb\u627e\u4e00\u79cd\u65e2\u80fd\u63d0\u5347\u6548\u7387\u53c8\u517c\u987e\u73af\u4fdd\u7684\u50ac\u5316\u5242\uff0c\u4e0d\u59a8\u8bd5\u8bd5\u8fd9\u6b3eDBU\u82c4\u57fa\u6c2f\u5316\u94f5\u76d0\u5427\uff01\u4e5f\u8bb8\u5b83\u5c31\u662f\u4f60\u4e0b\u4e00\u4e2a\u9879\u76ee\u7684\u201c\u7eff\u8272\u5f15\u64ce\u201d\u3002\ud83c\udf31<\/p>\n \n \ud83d\udccc \u4f5c\u8005\u6ce8<\/strong>\uff1a\u672c\u6587\u5185\u5bb9\u57fa\u4e8e\u516c\u5f00\u8d44\u6599\u6574\u7406\uff0c\u65e8\u5728\u79d1\u666e\u4e0e\u63a8\u5e7f\u7eff\u8272\u5316\u5b66\u7406\u5ff5\uff0c\u4e0d\u4ee3\u8868\u4efb\u4f55\u5546\u4e1a\u7acb\u573a\u3002\u6587\u4e2d\u6570\u636e\u4ec5\u4f9b\u53c2\u8003\uff0c\u8bf7\u4ee5\u5b9e\u9645\u5b9e\u9a8c\u7ed3\u679c\u4e3a\u51c6\u3002<\/p>\n \n \ud83d\udcac \u4e92\u52a8\u8bdd\u9898<\/strong>\uff1a\u4f60\u5728\u5b9e\u9a8c\u4e2d\u9047\u5230\u8fc7\u54ea\u4e9b\u201c\u73af\u4fdd\u96be\u9898\u201d\uff1f\u6b22\u8fce\u7559\u8a00\u4ea4\u6d41\uff0c\u8bf4\u4e0d\u5b9a\u4f60\u7684\u7ecf\u9a8c\u80fd\u5e2e\u522b\u4eba\u5c11\u8d70\u5f2f\u8def\u54e6\uff5e <\/p>\n \u4e1a\u52a1\u8054\u7cfb\uff1a\u5434\u7ecf\u7406 183-0190-3156<\/a> \u5fae\u4fe1\u540c\u53f7<\/h2>\n <\/strong><\/p>\n","protected":false},"excerpt":{"rendered":" \u65b0\u578bDBU\u82c4\u57fa\u6c2f\u5316\u94f5\u76d0\u7684\u73af\u4fdd\u7279\u6027\u63a2\u8ba8\uff1a\u7eff\u8272\u5316\u5b66\u4e2d\u7684\u65b0\u661f \u5f15\u5b50\uff1a\u4ece\u201c\u81ed\u5473\u5b9e\u9a8c\u5ba4\u201d\u5230\u201c\u7eff\u8272\u5316\u5de5\u201d \u4f60\u6709\u6ca1\u6709\u8fdb\u8fc7\u5316\u5b66\u5b9e\u9a8c\u5ba4\uff1f\u90a3\u80a1\u6325\u4e4b\u4e0d\u53bb\u7684\u523a\u9f3b\u5473\u9053\uff0c\u662f\u4e0d\u662f\u8ba9\u4f60\u4e00\u8fdb\u95e8\u5c31\u60f3\u6253\u55b7\u568f\uff1f\u5f88\u591a\u6709\u673a\u5408\u6210\u53cd\u5e94\u4e2d\u4f1a\u91ca\u653e\u51fa\u4e00\u4e9b\u4e0d\u90a3\u4e48\u53cb\u597d\u7684\u6c14\u5473\u548c\u6bd2\u6027\u7269\u8d28\u3002\u800c\u4eca\u5929\u6211\u4eec\u8981\u804a\u7684\u8fd9\u4e2a\u5316\u5408\u7269\u2014\u2014\u65b0\u578bDBU\u82c4\u57fa\u6c2f\u5316\u94f5\u76d0\uff0c\u6216\u8bb8\u6b63\u662f\u89e3\u51b3\u8fd9\u4e9b\u95ee\u9898\u7684\u5173\u952e\u4e4b\u4e00\u3002 \u5b83\u4e0d …<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":[],"categories":[3],"tags":[],"_links":{"self":[{"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/posts\/10207"}],"collection":[{"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/comments?post=10207"}],"version-history":[{"count":0,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/posts\/10207\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/media?parent=10207"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/categories?post=10207"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/tags?post=10207"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}