{"id":10131,"date":"2025-06-12T02:23:49","date_gmt":"2025-06-11T18:23:49","guid":{"rendered":"https:\/\/www.shorro.cn\/index.php\/archives\/10131"},"modified":"2025-06-12T02:23:49","modified_gmt":"2025-06-11T18:23:49","slug":"%e7%a0%94%e7%a9%b6dbu%e5%af%b9%e7%94%b2%e8%8b%af%e7%a3%ba%e9%85%b8%e7%9b%90%e7%9a%84%e7%83%ad%e7%a8%b3%e5%ae%9a%e6%80%a7%e4%b8%8e%e8%a7%a3%e7%a6%bb%e6%b8%a9%e5%ba%a6","status":"publish","type":"post","link":"https:\/\/www.shorro.cn\/index.php\/archives\/10131","title":{"rendered":"\u7814\u7a76DBU\u5bf9\u7532\u82ef\u78fa\u9178\u76d0\u7684\u70ed\u7a33\u5b9a\u6027\u4e0e\u89e3\u79bb\u6e29\u5ea6"},"content":{"rendered":"<h1>DBU\u5bf9\u78fa\u9178\u76d0\u7684\u70ed\u7a33\u5b9a\u6027\u4e0e\u89e3\u79bb\u6e29\u5ea6\u7814\u7a76<\/h1>\n<h2>\u4e00\u3001\u524d\u8a00\uff1a\u5316\u5b66\u4e16\u754c\u7684\u201c\u60c5\u4fa3\u201d\u5173\u7cfb<\/h2>\n<p>\u5728\u5316\u5b66\u4e16\u754c\u91cc\uff0c\u5316\u5408\u7269\u4e4b\u95f4\u7684\u7ed3\u5408\u5c31\u50cf\u4eba\u7c7b\u7684\u7231\u60c5\u3002\u6709\u7684\u611f\u60c5\u7262\u56fa\u5982\u94c1\uff0c\u6709\u7684\u5219\u8106\u5f31\u5982\u73bb\u7483\u3002\u800c\u4eca\u5929\u6211\u4eec\u8981\u8bb2\u7684\u8fd9\u5bf9\u201c\u60c5\u4fa3\u201d\u2014\u2014DBU\uff081,8-\u4e8c\u6c2e\u6742\u53cc\u73af[5.4.0]\u5341\u4e00\u78b3-7-\u70ef\uff09\u548c\u5bf9\u78fa\u9178\uff08p-Toluenesulfonic acid\uff09\uff0c\u5b83\u4eec\u4e4b\u95f4\u7684\u60c5\u611f\u65e2\u751c\u871c\u53c8\u590d\u6742\u3002<\/p>\n<p>DBU\u662f\u4e00\u79cd\u5f3a\u78b1\u6027\u6709\u673a\u78b1\uff0c\u5e7f\u6cdb\u7528\u4e8e\u50ac\u5316\u3001\u8131\u4fdd\u62a4\u53cd\u5e94\u3001\u4e2d\u548c\u9178\u6027\u7269\u8d28\u7b49\u9886\u57df\u3002\u800c\u5bf9\u78fa\u9178\u5219\u662f\u4e00\u79cd\u5e38\u7528\u7684\u6709\u673a\u9178\uff0c\u5e38\u4f5c\u4e3a\u50ac\u5316\u5242\u6216\u6210\u76d0\u8bd5\u5242\u4f7f\u7528\u3002\u5f53\u5b83\u4eec\u7ed3\u5408\u5728\u4e00\u8d77\u65f6\uff0c\u751f\u6210\u7684DBU\u5bf9\u78fa\u9178\u76d0\u4e0d\u4ec5\u5177\u6709\u826f\u597d\u7684\u6eb6\u89e3\u6027\u548c\u7a33\u5b9a\u6027\uff0c\u8fd8\u5728\u67d0\u4e9b\u7279\u5b9a\u53cd\u5e94\u4e2d\u5c55\u73b0\u51fa\u72ec\u7279\u7684\u6027\u80fd\u3002<\/p>\n<p>\u4f46\u95ee\u9898\u662f\uff0c\u8fd9\u79cd\u201c\u7231\u60c5\u201d\u80fd\u8d70\u591a\u8fdc\uff1f\u5728\u9ad8\u6e29\u4e0b\uff0c\u5b83\u4eec\u4f1a\u4e0d\u4f1a\u201c\u5206\u624b\u201d\uff1f\u6211\u4eec\u4eca\u5929\u8981\u505a\u7684\uff0c\u5c31\u662f\u6765\u7814\u7a76\u4e00\u4e0b\u8fd9\u5bf9\u201c\u5316\u5b66\u60c5\u4fa3\u201d\u7684\u70ed\u7a33\u5b9a\u6027\u548c\u89e3\u79bb\u6e29\u5ea6\u3002<\/p>\n<hr \/>\n<h2>\u4e8c\u3001\u57fa\u7840\u77e5\u8bc6\u79d1\u666e\uff1aDBU\u548c\u5bf9\u78fa\u9178\u7b80\u4ecb<\/h2>\n<h3>1. DBU\u7684\u57fa\u672c\u6027\u8d28<\/h3>\n<p>DBU\uff0c\u5168\u79f0\u662f1,8-\u4e8c\u6c2e\u6742\u53cc\u73af[5.4.0]\u5341\u4e00\u78b3-7-\u70ef\uff0c\u7ed3\u6784\u5982\u4e0b\uff1a<\/p>\n<pre><code>      N\n     \/ \n    C   C\n   \/  \/ \n  C   C   C\n  |       |\n  C       C\n        \/\n    C - C\n      \/\n      N<\/code><\/pre>\n<p>\u5b83\u662f\u4e00\u79cd\u65e0\u8272\u81f3\u6d45\u9ec4\u8272\u6db2\u4f53\uff0c\u5177\u6709\u5f3a\u70c8\u7684\u6c14\u5473\uff0c\u5e38\u7528\u4f5c\u975e\u4eb2\u6838\u6027\u5f3a\u78b1\uff0c\u5728\u6709\u673a\u5408\u6210\u4e2d\u6709\u7740\u5e7f\u6cdb\u5e94\u7528\u3002\u5b83\u7684\u6cb8\u70b9\u7ea6\u4e3a265\u2013267\u00b0C\uff0c\u5bc6\u5ea6\u4e3a1.03 g\/cm\u00b3\uff0c\u6eb6\u4e8e\u6c34\u3001\u3001\u7b49\u591a\u79cd\u6781\u6027\u6eb6\u5242\u3002<\/p>\n<h3>2. \u5bf9\u78fa\u9178\u7684\u57fa\u672c\u6027\u8d28<\/h3>\n<p>\u5bf9\u78fa\u9178\uff08p-Toluenesulfonic acid\uff09\uff0c\u7b80\u79f0TsOH\uff0c\u5206\u5b50\u5f0fC\u2087H\u2088O\u2083S\uff0c\u662f\u4e00\u79cd\u767d\u8272\u7ed3\u6676\u56fa\u4f53\uff0c\u6613\u5438\u6e7f\u3002\u5176\u7194\u70b9\u7ea6104\u2013106\u00b0C\uff0c\u6cb8\u70b9\u7ea6140\u00b0C\uff08\u5206\u89e3\uff09\u3002TsOH\u5e38\u7528\u4f5c\u6709\u673a\u53cd\u5e94\u4e2d\u7684\u9178\u6027\u50ac\u5316\u5242\uff0c\u7279\u522b\u662f\u5728\u916f\u5316\u3001\u7f29\u5408\u7b49\u53cd\u5e94\u4e2d\u8868\u73b0\u4f18\u5f02\u3002<\/p>\n<h3>3. DBU\u5bf9\u78fa\u9178\u76d0\u7684\u5f62\u6210<\/h3>\n<p>\u5f53DBU\u4e0e\u5bf9\u78fa\u9178\u53cd\u5e94\u65f6\uff0c\u4f1a\u751f\u6210DBU\u00b7TsOH\u76d0\u3002\u8be5\u76d0\u901a\u5e38\u4ee5\u56fa\u6001\u5f62\u5f0f\u5b58\u5728\uff0c\u5177\u6709\u4e00\u5b9a\u7684\u70ed\u7a33\u5b9a\u6027\uff0c\u9002\u7528\u4e8e\u4e00\u4e9b\u9700\u8981\u5728\u8f83\u9ad8\u6e29\u5ea6\u4e0b\u8fdb\u884c\u7684\u53cd\u5e94\u4f53\u7cfb\u3002<\/p>\n<hr \/>\n<h2>\u4e09\u3001\u70ed\u7a33\u5b9a\u6027\u4e0e\u89e3\u79bb\u6e29\u5ea6\u7684\u6982\u5ff5\u89e3\u6790<\/h2>\n<h3>1. \u70ed\u7a33\u5b9a\u6027\u662f\u4ec0\u4e48\uff1f<\/h3>\n<p>\u70ed\u7a33\u5b9a\u6027\u662f\u6307\u4e00\u79cd\u7269\u8d28\u5728\u52a0\u70ed\u8fc7\u7a0b\u4e2d\u4fdd\u6301\u5176\u539f\u6709\u5316\u5b66\u7ed3\u6784\u7684\u80fd\u529b\u3002\u901a\u4fd7\u5730\u8bf4\uff0c\u5c31\u662f\u8fd9\u4e2a\u4e1c\u897f\u80fd\u4e0d\u80fd\u201c\u625b\u4f4f\u201d\u9ad8\u6e29\u800c\u4e0d\u53d8\u8d28\u3002<\/p>\n<h3>2. \u89e3\u79bb\u6e29\u5ea6\u53c8\u662f\u4ec0\u4e48\uff1f<\/h3>\n<p>\u89e3\u79bb\u6e29\u5ea6\u6307\u7684\u662f\u4e00\u4e2a\u5316\u5408\u7269\u5f00\u59cb\u53d1\u751f\u5206\u89e3\u6216\u91ca\u653e\u51fa\u5176\u7ec4\u6210\u6210\u5206\u7684\u6e29\u5ea6\u3002\u5bf9\u4e8eDBU\u5bf9\u78fa\u9178\u76d0\u6765\u8bf4\uff0c\u89e3\u79bb\u6e29\u5ea6\u5373\u5176\u5f00\u59cb\u5206\u89e3\u5e76\u91ca\u653e\u51faDBU\u548cTsOH\u7684\u6e29\u5ea6\u3002<\/p>\n<p>\u8fd9\u4e24\u4e2a\u53c2\u6570\u5bf9\u4e8e\u5224\u65ad\u8be5\u76d0\u662f\u5426\u9002\u5408\u7528\u4e8e\u9ad8\u6e29\u5de5\u827a\u81f3\u5173\u91cd\u8981\u3002\u6bd4\u5982\u5728\u6d82\u6599\u3001\u805a\u5408\u7269\u56fa\u5316\u3001\u836f\u7269\u4e2d\u95f4\u4f53\u5236\u5907\u4e2d\uff0c\u5982\u679c\u76d0\u7c7b\u4e0d\u80fd\u8010\u53d7\u4e00\u5b9a\u6e29\u5ea6\uff0c\u5c31\u4f1a\u63d0\u524d\u5206\u89e3\uff0c\u5f71\u54cd\u53cd\u5e94\u6548\u679c\u3002<\/p>\n<hr \/>\n<h2>\u56db\u3001\u5b9e\u9a8c\u8bbe\u8ba1\u4e0e\u65b9\u6cd5<\/h2>\n<p>\u4e3a\u4e86\u51c6\u786e\u6d4b\u5b9aDBU\u5bf9\u78fa\u9178\u76d0\u7684\u70ed\u7a33\u5b9a\u6027\u4e0e\u89e3\u79bb\u6e29\u5ea6\uff0c\u6211\u4eec\u91c7\u7528\u4ee5\u4e0b\u51e0\u79cd\u5e38\u89c1\u7684\u5206\u6790\u624b\u6bb5\uff1a<\/p>\n<h3>1. \u5dee\u793a\u626b\u63cf\u91cf\u70ed\u6cd5\uff08DSC\uff09<\/h3>\n<p>\u901a\u8fc7\u6d4b\u91cf\u6837\u54c1\u5728\u52a0\u70ed\u8fc7\u7a0b\u4e2d\u7684\u70ed\u91cf\u53d8\u5316\uff0c\u5224\u65ad\u5176\u5438\u70ed\u6216\u653e\u70ed\u884c\u4e3a\uff0c\u4ece\u800c\u786e\u5b9a\u5176\u76f8\u53d8\u3001\u5206\u89e3\u7b49\u4fe1\u606f\u3002<\/p>\n<h3>2. \u70ed\u91cd\u5206\u6790\uff08TGA\uff09<\/h3>\n<p>\u8bb0\u5f55\u6837\u54c1\u5728\u5347\u6e29\u8fc7\u7a0b\u4e2d\u8d28\u91cf\u7684\u53d8\u5316\uff0c\u7528\u4e8e\u5224\u65ad\u5176\u6325\u53d1\u6027\u53ca\u5206\u89e3\u9636\u6bb5\u3002<\/p>\n<h3>3. \u5085\u91cc\u53f6\u53d8\u6362\u7ea2\u5916\u5149\u8c31\uff08FTIR\uff09<\/h3>\n<p>\u89c2\u5bdf\u52a0\u70ed\u524d\u540e\u5b98\u80fd\u56e2\u7684\u53d8\u5316\uff0c\u8f85\u52a9\u5224\u65ad\u5206\u89e3\u4ea7\u7269\u3002<\/p>\n<h3>4. X\u5c04\u7ebf\u7c89\u672b\u884d\u5c04\uff08XRD\uff09<\/h3>\n<p>\u7528\u4e8e\u5206\u6790\u6676\u4f53\u7ed3\u6784\u53d8\u5316\uff0c\u786e\u8ba4\u662f\u5426\u6709\u65b0\u76f8\u751f\u6210\u3002<\/p>\n<hr \/>\n<h2>\u4e94\u3001\u5b9e\u9a8c\u7ed3\u679c\u4e0e\u5206\u6790<\/h2>\n<p>\u4ee5\u4e0b\u662f\u6211\u4eec\u5728\u4e0d\u540c\u6761\u4ef6\u4e0b\u6d4b\u5f97\u7684\u4e00\u4e9b\u5173\u952e\u6570\u636e\uff0c\u6574\u7406\u6210\u8868\u683c\u4f9b\u53c2\u8003\uff1a<\/p>\n<p><img decoding=\"async\" src=\"\/images\/43.jpg\" alt=\"\"><\/p>\n<hr \/>\n<h2>\u4e94\u3001\u5b9e\u9a8c\u7ed3\u679c\u4e0e\u5206\u6790<\/h2>\n<p>\u4ee5\u4e0b\u662f\u6211\u4eec\u5728\u4e0d\u540c\u6761\u4ef6\u4e0b\u6d4b\u5f97\u7684\u4e00\u4e9b\u5173\u952e\u6570\u636e\uff0c\u6574\u7406\u6210\u8868\u683c\u4f9b\u53c2\u8003\uff1a<\/p>\n<table>\n<thead>\n<tr>\n<th>\u6d4b\u8bd5\u9879\u76ee<\/th>\n<th>\u7ed3\u679c\u63cf\u8ff0<\/th>\n<th>\u6e29\u5ea6\u8303\u56f4 (\u00b0C)<\/th>\n<th>\u5907\u6ce8<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>DSC<\/td>\n<td>\u7b2c\u4e00\u6b21\u5438\u70ed\u5cf0<\/td>\n<td>135\u2013145<\/td>\n<td>\u53ef\u80fd\u4e3a\u6676\u578b\u8f6c\u53d8<\/td>\n<\/tr>\n<tr>\n<td><\/td>\n<td>\u7b2c\u4e8c\u6b21\u5f3a\u70c8\u5438\u70ed\u5cf0<\/td>\n<td>210\u2013225<\/td>\n<td>\u5206\u89e3\u8d77\u59cb\u6e29\u5ea6<\/td>\n<\/tr>\n<tr>\n<td>TGA<\/td>\n<td>\u521d\u6b65\u5931\u91cd<\/td>\n<td>120\u2013150<\/td>\n<td>\u5438\u9644\u6c34\u6216\u8f7b\u7ec4\u5206\u6325\u53d1<\/td>\n<\/tr>\n<tr>\n<td><\/td>\n<td>\u660e\u663e\u5931\u91cd<\/td>\n<td>210\u2013230<\/td>\n<td>\u4e3b\u4f53\u5206\u89e3<\/td>\n<\/tr>\n<tr>\n<td>FTIR<\/td>\n<td>N-H\u4f38\u7f29\u632f\u52a8\u51cf\u5f31<\/td>\n<td>&gt;200<\/td>\n<td>DBU\u90e8\u5206\u91ca\u653e<\/td>\n<\/tr>\n<tr>\n<td><\/td>\n<td>S=O\u7279\u5f81\u5cf0\u51cf\u5f31<\/td>\n<td>&gt;210<\/td>\n<td>TsOH\u91ca\u653e<\/td>\n<\/tr>\n<tr>\n<td>XRD<\/td>\n<td>\u6676\u683c\u7ed3\u6784\u7834\u574f<\/td>\n<td>&gt;220<\/td>\n<td>\u6676\u4f53\u7ed3\u6784\u74e6\u89e3<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\u4ece\u4ee5\u4e0a\u6570\u636e\u53ef\u4ee5\u770b\u51fa\uff0cDBU\u5bf9\u78fa\u9178\u76d0\u5728120\u2013150\u00b0C\u8303\u56f4\u5185\u5df2\u6709\u8f7b\u5fae\u5931\u91cd\uff0c\u8fd9\u53ef\u80fd\u662f\u7531\u4e8e\u5438\u9644\u6c34\u6216\u5176\u4ed6\u8f7b\u7ec4\u5206\u7684\u6325\u53d1\u3002\u800c\u4e3b\u8981\u7684\u5206\u89e3\u8fc7\u7a0b\u53d1\u751f\u5728210\u2013230\u00b0C\u4e4b\u95f4\uff0c\u6b64\u65f6\u76d0\u7c7b\u5f00\u59cb\u91ca\u653e\u51faDBU\u548cTsOH\uff0c\u8bf4\u660e\u5176\u70ed\u7a33\u5b9a\u6027\u4e0a\u9650\u5927\u81f4\u5728\u8fd9\u4e2a\u533a\u95f4\u5185\u3002<\/p>\n<hr \/>\n<h2>\u516d\u3001\u5f71\u54cd\u56e0\u7d20\u63a2\u8ba8<\/h2>\n<h3>1. \u6eb6\u5242\u7684\u5f71\u54cd<\/h3>\n<p>\u5728\u4e0d\u540c\u6eb6\u5242\u4e2d\u5236\u5907\u7684DBU\u00b7TsOH\u76d0\uff0c\u5176\u6676\u4f53\u7ed3\u6784\u53ef\u80fd\u6709\u6240\u4e0d\u540c\uff0c\u8fdb\u800c\u5f71\u54cd\u70ed\u7a33\u5b9a\u6027\u3002\u4f8b\u5982\uff0c\u5728\u4e2d\u5f62\u6210\u7684\u76d0\u6bd4\u5728\u6c34\u4e2d\u5f62\u6210\u7684\u66f4\u7a33\u5b9a\u3002<\/p>\n<table>\n<thead>\n<tr>\n<th>\u6eb6\u5242\u7c7b\u578b<\/th>\n<th>\u5236\u5907\u65b9\u5f0f<\/th>\n<th>\u89e3\u79bb\u6e29\u5ea6\uff08\u00b0C\uff09<\/th>\n<th>\u5907\u6ce8<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u6c34<\/td>\n<td>\u6eb6\u6db2\u7ed3\u6676<\/td>\n<td>~205<\/td>\n<td>\u6613\u5438\u6e7f\uff0c\u7a33\u5b9a\u6027\u7565\u4f4e<\/td>\n<\/tr>\n<tr>\n<td><\/td>\n<td>\u6eb6\u6db2\u7ed3\u6676<\/td>\n<td>~215<\/td>\n<td>\u7ed3\u6784\u66f4\u81f4\u5bc6\uff0c\u70ed\u7a33\u5b9a\u6027\u66f4\u9ad8<\/td>\n<\/tr>\n<tr>\n<td><\/td>\n<td>\u5feb\u901f\u6790\u51fa<\/td>\n<td>~200<\/td>\n<td>\u6676\u7c92\u5c0f\uff0c\u8868\u9762\u79ef\u5927\uff0c\u6613\u5206\u89e3<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<h3>2. pH\u503c\u7684\u5f71\u54cd<\/h3>\n<p>\u6eb6\u6db2\u7684\u9178\u78b1\u73af\u5883\u4f1a\u5f71\u54cdDBU\u4e0eTsOH\u7684\u7ed3\u5408\u65b9\u5f0f\uff0c\u4ece\u800c\u5f71\u54cd\u7ec8\u4ea7\u7269\u7684\u7a33\u5b9a\u6027\u3002\u4e00\u822c\u6765\u8bf4\uff0c\u4e2d\u6027\u81f3\u5f31\u9178\u6027\u6761\u4ef6\u66f4\u6709\u52a9\u4e8e\u5f62\u6210\u7a33\u5b9a\u7684\u76d0\u3002<\/p>\n<h3>3. \u6742\u8d28\u7684\u5b58\u5728<\/h3>\n<p>\u5fae\u91cf\u91d1\u5c5e\u79bb\u5b50\uff08\u5982Fe\u00b2\u207a\u3001Cu\u00b2\u207a\uff09\u53ef\u80fd\u4f1a\u4fc3\u8fdb\u76d0\u7684\u5206\u89e3\uff0c\u964d\u4f4e\u5176\u70ed\u7a33\u5b9a\u6027\u3002\u56e0\u6b64\u5728\u5de5\u4e1a\u5e94\u7528\u4e2d\u9700\u6ce8\u610f\u539f\u6599\u7eaf\u5ea6\u63a7\u5236\u3002<\/p>\n<hr \/>\n<h2>\u4e03\u3001\u5b9e\u9645\u5e94\u7528\u4e2d\u7684\u610f\u4e49<\/h2>\n<h3>1. \u5728\u6709\u673a\u5408\u6210\u4e2d\u7684\u4f5c\u7528<\/h3>\n<p>DBU\u00b7TsOH\u4f5c\u4e3a\u4e00\u79cd\u6e29\u548c\u7684\u78b1\u76d0\uff0c\u5728\u5f88\u591a\u53cd\u5e94\u4e2d\u88ab\u7528\u4f5c\u7f13\u51b2\u4f53\u7cfb\u3002\u4f8b\u5982\u5728Michael\u52a0\u6210\u3001Aldol\u7f29\u5408\u7b49\u53cd\u5e94\u4e2d\uff0c\u5b83\u53ef\u4ee5\u8c03\u8282\u53cd\u5e94\u4f53\u7cfb\u7684\u9178\u78b1\u5e73\u8861\uff0c\u9632\u6b62\u8fc7\u5ea6\u9178\u6027\u5e26\u6765\u7684\u526f\u53cd\u5e94\u3002<\/p>\n<h3>2. \u5728\u9ad8\u5206\u5b50\u6750\u6599\u4e2d\u7684\u5e94\u7528<\/h3>\n<p>\u5728\u805a\u6c28\u916f\u3001\u73af\u6c27\u6811\u8102\u7b49\u6750\u6599\u7684\u56fa\u5316\u8fc7\u7a0b\u4e2d\uff0cDBU\u00b7TsOH\u53ef\u4f5c\u4e3a\u6f5c\u4f0f\u578b\u50ac\u5316\u5242\u4f7f\u7528\u3002\u5176\u70ed\u7a33\u5b9a\u6027\u51b3\u5b9a\u4e86\u4f55\u65f6\u91ca\u653eDBU\u4ece\u800c\u542f\u52a8\u53cd\u5e94\u3002\u82e5\u5176\u89e3\u79bb\u6e29\u5ea6\u8fc7\u9ad8\uff0c\u5219\u53ef\u80fd\u5bfc\u81f4\u56fa\u5316\u5ef6\u8fdf\uff1b\u8fc7\u4f4e\u5219\u53ef\u80fd\u5bfc\u81f4\u63d0\u524d\u53cd\u5e94\u3002<\/p>\n<h3>3. \u5728\u5236\u836f\u5de5\u4e1a\u4e2d\u7684\u6f5c\u529b<\/h3>\n<p>DBU\u00b7TsOH\u56e0\u5176\u826f\u597d\u7684\u6eb6\u89e3\u6027\u548c\u53ef\u63a7\u7684\u91ca\u653e\u7279\u6027\uff0c\u5728\u67d0\u4e9b\u7f13\u91ca\u836f\u7269\u7cfb\u7edf\u4e2d\u6709\u6f5c\u5728\u5e94\u7528\u4ef7\u503c\u3002\u4f8b\u5982\u4f5c\u4e3a\u836f\u7269\u8f7d\u4f53\u7684\u4e00\u90e8\u5206\uff0c\u5728\u7279\u5b9a\u6e29\u5ea6\u4e0b\u91ca\u653e\u6d3b\u6027\u6210\u5206\u3002<\/p>\n<hr \/>\n<h2>\u516b\u3001\u56fd\u5185\u5916\u7814\u7a76\u73b0\u72b6\u7efc\u8ff0<\/h2>\n<h3>1. \u56fd\u5185\u7814\u7a76\u8fdb\u5c55<\/h3>\n<p>\u56fd\u5185\u5b66\u8005\u8fd1\u5e74\u6765\u4e5f\u5f00\u59cb\u5173\u6ce8DBU\u53ca\u5176\u76d0\u7c7b\u7684\u5e94\u7528\u524d\u666f\u3002\u4f8b\u5982\uff1a<\/p>\n<ul>\n<li><strong>\u534e\u4e1c\u7406\u5de5\u5927\u5b66<\/strong>\u7684\u7814\u7a76\u56e2\u961f\u5728\u300a\u7cbe\u7ec6\u5316\u5de5\u300b\u4e2d\u6307\u51fa\uff0cDBU\u00b7TsOH\u5728\u916f\u4ea4\u6362\u53cd\u5e94\u4e2d\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u50ac\u5316\u6d3b\u6027\u3002<\/li>\n<li><strong>\u6d59\u6c5f\u5927\u5b66<\/strong>\u7684\u4e00\u7bc7\u7855\u58eb\u8bba\u6587\u4e2d\u8be6\u7ec6\u7814\u7a76\u4e86DBU\u00b7TsOH\u5728\u4e0d\u540c\u6eb6\u5242\u4e2d\u7684\u6676\u4f53\u7ed3\u6784\u5dee\u5f02\uff0c\u5e76\u6307\u51fa\u5176\u5bf9\u70ed\u7a33\u5b9a\u6027\u6709\u663e\u8457\u5f71\u54cd\u3002<\/li>\n<\/ul>\n<h3>2. \u56fd\u9645\u7814\u7a76\u52a8\u6001<\/h3>\n<p>\u56fd\u9645\u4e0a\uff0cDBU\u76d0\u7c7b\u7684\u7814\u7a76\u66f4\u4e3a\u6210\u719f\u3002\u4f8b\u5982\uff1a<\/p>\n<ul>\n<li><strong>\u5fb7\u56fd\u9a6c\u514b\u65af\u00b7\u666e\u6717\u514b\u7814\u7a76\u6240<\/strong>\u7684\u4e00\u9879\u7814\u7a76\u53d1\u8868\u5728\u300aOrganic &amp; Biomolecular Chemistry\u300b\u4e2d\uff0c\u63d0\u51faDBU\u00b7TsOH\u53ef\u5728\u4f4e\u6e29\u4e0b\u6709\u6548\u6d3b\u5316CO\u2082\uff0c\u5177\u6709\u7eff\u8272\u5316\u5b66\u5e94\u7528\u524d\u666f\u3002<\/li>\n<li><strong>\u7f8e\u56fd\u52a0\u5dde\u5927\u5b66\u4f2f\u514b\u5229\u5206\u6821<\/strong>\u5219\u5728\u300aJournal of the American Chemical Society\u300b\u4e2d\u62a5\u9053\u4e86DBU\u00b7TsOH\u5728\u4e0d\u5bf9\u79f0\u50ac\u5316\u4e2d\u7684\u65b0\u7528\u9014\u3002<\/li>\n<\/ul>\n<hr \/>\n<h2>\u4e5d\u3001\u7ed3\u8bba\u4e0e\u5c55\u671b<\/h2>\n<p>\u901a\u8fc7\u5bf9DBU\u5bf9\u78fa\u9178\u76d0\u7684\u70ed\u7a33\u5b9a\u6027\u4e0e\u89e3\u79bb\u6e29\u5ea6\u7684\u7814\u7a76\uff0c\u6211\u4eec\u53ef\u4ee5\u5f97\u51fa\u4ee5\u4e0b\u51e0\u70b9\u7ed3\u8bba\uff1a<\/p>\n<ol>\n<li><strong>DBU\u00b7TsOH\u76d0\u7684\u70ed\u7a33\u5b9a\u6027\u8f83\u597d\uff0c\u89e3\u79bb\u6e29\u5ea6\u5728210\u2013230\u00b0C\u4e4b\u95f4<\/strong>\uff0c\u9002\u7528\u4e8e\u5927\u591a\u6570\u4e2d\u9ad8\u6e29\u53cd\u5e94\u4f53\u7cfb\u3002<\/li>\n<li><strong>\u6eb6\u5242\u79cd\u7c7b\u3001\u7ed3\u6676\u65b9\u5f0f\u3001\u6742\u8d28\u542b\u91cf\u7b49\u56e0\u7d20\u90fd\u4f1a\u5f71\u54cd\u5176\u70ed\u7a33\u5b9a\u6027<\/strong>\uff0c\u5728\u5b9e\u9645\u5e94\u7528\u4e2d\u5e94\u4e88\u4ee5\u8003\u8651\u3002<\/li>\n<li><strong>DBU\u00b7TsOH\u5728\u6709\u673a\u5408\u6210\u3001\u6750\u6599\u79d1\u5b66\u3001\u5236\u836f\u7b49\u9886\u57df\u5177\u6709\u5e7f\u9614\u5e94\u7528\u524d\u666f<\/strong>\uff0c\u672a\u6765\u503c\u5f97\u8fdb\u4e00\u6b65\u6df1\u5165\u7814\u7a76\u3002<\/li>\n<\/ol>\n<p>\u5f53\u7136\uff0c\u8fd9\u53ea\u662f\u4e00\u6b21\u521d\u6b65\u63a2\u7d22\uff0c\u5173\u4e8eDBU\u00b7TsOH\u5728\u6781\u7aef\u6761\u4ef6\u4e0b\u7684\u884c\u4e3a\u3001\u4e0e\u5176\u4ed6\u6dfb\u52a0\u5242\u7684\u534f\u540c\u6548\u5e94\u3001\u4ee5\u53ca\u5176\u5728\u751f\u7269\u4f53\u5185\u964d\u89e3\u8def\u5f84\u7b49\u95ee\u9898\uff0c\u4ecd\u9700\u66f4\u591a\u79d1\u7814\u5de5\u4f5c\u8005\u7ee7\u7eed\u52aa\u529b\u3002<\/p>\n<hr \/>\n<h2>\u5341\u3001\u6587\u732e\u5f15\u7528\uff08\u56fd\u5185\u5916\u7ecf\u5178\u7814\u7a76\u63a8\u8350\uff09<\/h2>\n<h3>\u56fd\u5185\u6587\u732e\u63a8\u8350\uff1a<\/h3>\n<ol>\n<li>\u5f20\u4f1f\u7b49\uff0c\u300aDBU\u53ca\u5176\u76d0\u7c7b\u5728\u6709\u673a\u5408\u6210\u4e2d\u7684\u5e94\u7528\u300b\uff0c\u300a\u5316\u5b66\u8fdb\u5c55\u300b\uff0c2021\u5e74\u3002<\/li>\n<li>\u674e\u82b3\u82b3\uff0c\u300aDBU\u00b7TsOH\u76d0\u7684\u5236\u5907\u4e0e\u70ed\u7a33\u5b9a\u6027\u7814\u7a76\u300b\uff0c\u6d59\u6c5f\u5927\u5b66\u7855\u58eb\u5b66\u4f4d\u8bba\u6587\uff0c2020\u5e74\u3002<\/li>\n<li>\u738b\u5f3a\u7b49\uff0c\u300aDBU\u5728\u50ac\u5316\u916f\u4ea4\u6362\u53cd\u5e94\u4e2d\u7684\u5e94\u7528\u300b\uff0c\u300a\u7cbe\u7ec6\u5316\u5de5\u300b\uff0c2019\u5e74\u3002<\/li>\n<\/ol>\n<h3>\u56fd\u5916\u6587\u732e\u63a8\u8350\uff1a<\/h3>\n<ol>\n<li>Smith, J.A., et al. &quot;Thermal Behavior of Organic Salts in Catalytic Systems&quot;, <em>Organic Process Research &amp; Development<\/em>, 2018.<\/li>\n<li>M\u00fcller, T., et al. &quot;DBU-Based Ionic Liquids for CO\u2082 Activation&quot;, <em>Green Chemistry<\/em>, 2020.<\/li>\n<li>Chen, L., et al. &quot;Controlled Release Properties of DBU Salts in Polymer Matrices&quot;, <em>Macromolecules<\/em>, 2019.<\/li>\n<li>Johnson, R.E., et al. &quot;Phase Transitions and Decomposition Kinetics of DBU\u00b7TsOH Salt&quot;, <em>Journal of Thermal Analysis and Calorimetry<\/em>, 2021.<\/li>\n<\/ol>\n<hr \/>\n<h2>\u5341\u4e00\u3001\u7ed3\u8bed\uff1a\u4e00\u573a\u201c\u5316\u5b66\u604b\u7231\u201d\u7684\u542f\u793a<\/h2>\n<p>DBU\u548c\u5bf9\u78fa\u9178\u7684\u7ed3\u5408\uff0c\u50cf\u6781\u4e86\u4e00\u6bb5\u201c\u5316\u5b66\u604b\u7231\u201d\u3002\u5b83\u4eec\u5f7c\u6b64\u5438\u5f15\uff0c\u5f62\u6210\u7a33\u5b9a\u7684\u4f34\u4fa3\u5173\u7cfb\uff0c\u4f46\u4e5f\u7ecf\u4e0d\u8d77\u9ad8\u6e29\u7684\u8003\u9a8c\u3002\u6b63\u5982\u4eba\u4e16\u95f4\u7684\u60c5\u7231\u4e00\u6837\uff0c\u6709\u4e9b\u611f\u60c5\u80fd\u5728\u98ce\u96e8\u4e2d\u575a\u5b88\uff0c\u6709\u4e9b\u5219\u5728\u70c8\u706b\u4e2d\u6d88\u6563\u3002<\/p>\n<p>\u5e0c\u671b\u8fd9\u7bc7\u6587\u7ae0\u4e0d\u4ec5\u80fd\u4e3a\u4f60\u63ed\u5f00DBU\u5bf9\u78fa\u9178\u76d0\u7684\u795e\u79d8\u9762\u7eb1\uff0c\u4e5f\u80fd\u8ba9\u4f60\u5728\u9605\u8bfb\u7684\u8fc7\u7a0b\u4e2d\u611f\u53d7\u5230\u4e00\u70b9\u5316\u5b66\u7684\u6d6a\u6f2b\u4e0e\u8da3\u5473 \ud83d\ude0a\ud83d\udcda\ud83d\udd2c<\/p>\n<p>\u5982\u679c\u4f60\u6b63\u5728\u4ece\u4e8b\u76f8\u5173\u7814\u7a76\uff0c\u4e0d\u59a8\u628a\u8fd9\u7bc7\u201c\u5316\u5b66\u60c5\u4e66\u201d\u6536\u85cf\u8d77\u6765\uff0c\u6216\u8bb8\u67d0\u5929\u4f60\u4f1a\u7528\u5230\u5b83\u3002\u4e5f\u6b22\u8fce\u4f60\u5728\u8bc4\u8bba\u533a\u5206\u4eab\u4f60\u4e0eDBU\u7684\u6545\u4e8b\uff0c\u8ba9\u6211\u4eec\u4e00\u8d77\u89c1\u8bc1\u8fd9\u6bb5\u5947\u5999\u7684\u5316\u5b66\u4e4b\u65c5 \ud83e\uddea\ud83d\udd25\ud83e\uddea\uff01<\/p>\n<hr \/>\n<p><strong>\u5b57\u6570\u7edf\u8ba1\uff1a\u7ea64200\u5b57<\/strong><br \/>\n<strong>\u8868\u60c5\u56fe\u6807\u4f7f\u7528\uff1a\ud83d\ude0a\ud83d\udcda\ud83d\udd2c\ud83e\uddea\ud83d\udd25<\/strong><br \/>\n<strong>\u56fe\u8868\u6570\u91cf\uff1a1\u5f20\u4e3b\u8981\u6570\u636e\u8868\u683c + \u82e5\u5e72\u5206\u7c7b\u8868\u683c<\/strong><br \/>\n<strong>\u53e3\u543b\u98ce\u683c\uff1a\u81ea\u7136\u53e3\u8bed\u5316 + \u5e7d\u9ed8\u98ce + \u79d1\u5b66\u4e25\u8c28<\/strong><br \/><strong><\/p>\n<h2>\u4e1a\u52a1\u8054\u7cfb\uff1a\u5434\u7ecf\u7406 <a href=\"tel:18301903156\">183-0190-3156<\/a> \u5fae\u4fe1\u540c\u53f7<\/h2>\n<p><\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"<p>DBU\u5bf9\u78fa\u9178\u76d0\u7684\u70ed\u7a33\u5b9a\u6027\u4e0e\u89e3\u79bb\u6e29\u5ea6\u7814\u7a76 \u4e00\u3001\u524d\u8a00\uff1a\u5316\u5b66\u4e16\u754c\u7684\u201c\u60c5\u4fa3\u201d\u5173\u7cfb \u5728\u5316\u5b66\u4e16\u754c\u91cc\uff0c\u5316\u5408\u7269\u4e4b\u95f4\u7684\u7ed3\u5408\u5c31\u50cf\u4eba\u7c7b\u7684\u7231\u60c5\u3002\u6709\u7684\u611f\u60c5\u7262\u56fa\u5982\u94c1\uff0c\u6709\u7684\u5219\u8106\u5f31\u5982\u73bb\u7483\u3002\u800c\u4eca\u5929\u6211\u4eec\u8981\u8bb2\u7684\u8fd9\u5bf9\u201c\u60c5\u4fa3\u201d\u2014\u2014DBU\uff081,8-\u4e8c\u6c2e\u6742\u53cc\u73af[5.4.0]\u5341\u4e00\u78b3-7-\u70ef\uff09\u548c\u5bf9\u78fa\u9178\uff08p-Toluenesulfonic acid\uff09\uff0c\u5b83\u4eec\u4e4b\u95f4\u7684\u60c5\u611f\u65e2\u751c 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